Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C 60 Fullerene and Spiropyran-A Promising Approach to the Creation of Anticancer Drugs
For the first time a pyrrolidinofullerene salt containing a spiropyran group and an ammonium group, capable of reversibly reacting to UV radiation, has been synthesized. Photoinduced reactions of the synthesized compounds were studied using absorption and luminescence spectroscopies, spectral and ki...
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Veröffentlicht in: | Molecules (Basel, Switzerland) Switzerland), 2023-01, Vol.28 (3) |
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creator | Khuzin, Artur A Galimov, Dim I Khuzina, Liliya L |
description | For the first time a pyrrolidinofullerene salt containing a spiropyran group and an ammonium group, capable of reversibly reacting to UV radiation, has been synthesized. Photoinduced reactions of the synthesized compounds were studied using absorption and luminescence spectroscopies, spectral and kinetic characteristics were measured. The hybrid molecule was found to exhibit intrinsic fluorescence even in the spirocyclic form. The C
derivative showed a higher stability and better spectral and luminescent properties than the precursor. |
doi_str_mv | 10.3390/molecules28031107 |
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derivative showed a higher stability and better spectral and luminescent properties than the precursor.</description><subject>Antineoplastic Agents</subject><subject>Fullerenes</subject><subject>Luminescence</subject><subject>Sodium Chloride</subject><subject>Sodium Chloride, Dietary</subject><subject>Ultraviolet Rays</subject><issn>1420-3049</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFj0tOwzAURS0kRMtnAUzQ20DAjkNDhyFQdQBSpTKvXOe1MfJPz84gG2KdFFrGjO4dXJ2jy9it4PdSzvmDCxb1YDGVT1wKweszNhVVyQvJq_mEXab0yXkpKvF4wSZyVte8rssp-1r1IQfdU3BGg_IdvA3OeEwafYYVhYiUDSYIO1CwVjYf23Lckung_WSFZ5Wwg-ChhRmHxWAtEnr8Ja6jOXBGUr5ofpDOJOP30MRIQekecoDcI7SEKpsD4iBofDZaeY0ELzTs0zU73ymb8OaUV-xu8frRLos4bB12m0jGKRo3f8fkv4NvwhdhYg</recordid><startdate>20230122</startdate><enddate>20230122</enddate><creator>Khuzin, Artur A</creator><creator>Galimov, Dim I</creator><creator>Khuzina, Liliya L</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><orcidid>https://orcid.org/0000-0002-6049-2890</orcidid><orcidid>https://orcid.org/0000-0001-6165-6343</orcidid></search><sort><creationdate>20230122</creationdate><title>Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C 60 Fullerene and Spiropyran-A Promising Approach to the Creation of Anticancer Drugs</title><author>Khuzin, Artur A ; Galimov, Dim I ; Khuzina, Liliya L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_367707723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Antineoplastic Agents</topic><topic>Fullerenes</topic><topic>Luminescence</topic><topic>Sodium Chloride</topic><topic>Sodium Chloride, Dietary</topic><topic>Ultraviolet Rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khuzin, Artur A</creatorcontrib><creatorcontrib>Galimov, Dim I</creatorcontrib><creatorcontrib>Khuzina, Liliya L</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><jtitle>Molecules (Basel, Switzerland)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khuzin, Artur A</au><au>Galimov, Dim I</au><au>Khuzina, Liliya L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C 60 Fullerene and Spiropyran-A Promising Approach to the Creation of Anticancer Drugs</atitle><jtitle>Molecules (Basel, Switzerland)</jtitle><addtitle>Molecules</addtitle><date>2023-01-22</date><risdate>2023</risdate><volume>28</volume><issue>3</issue><eissn>1420-3049</eissn><abstract>For the first time a pyrrolidinofullerene salt containing a spiropyran group and an ammonium group, capable of reversibly reacting to UV radiation, has been synthesized. Photoinduced reactions of the synthesized compounds were studied using absorption and luminescence spectroscopies, spectral and kinetic characteristics were measured. The hybrid molecule was found to exhibit intrinsic fluorescence even in the spirocyclic form. The C
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source | MEDLINE; DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central; Free Full-Text Journals in Chemistry |
subjects | Antineoplastic Agents Fullerenes Luminescence Sodium Chloride Sodium Chloride, Dietary Ultraviolet Rays |
title | Photochromic and Luminescent Properties of a Salt of a Hybrid Molecule Based on C 60 Fullerene and Spiropyran-A Promising Approach to the Creation of Anticancer Drugs |
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