Recent advances of mesoionic N-heterocyclic olefins
This Perspective article highlights the recent development of mesoionic N-heterocyclic olefins (mNHOs), where the exo-cyclic olefinic carbon is not bonded to strongly electron-withdrawing groups. The unquenched basicity and nucleophilicity of the exo-cyclic olefinic carbon make mNHOs strong σ-donors...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2022-06, Vol.51 (24), p.9191-9198 |
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| container_end_page | 9198 |
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| container_issue | 24 |
| container_start_page | 9191 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 51 |
| creator | Liang, Qiuming Song, Datong |
| description | This Perspective article highlights the recent development of mesoionic N-heterocyclic olefins (mNHOs), where the exo-cyclic olefinic carbon is not bonded to strongly electron-withdrawing groups. The unquenched basicity and nucleophilicity of the exo-cyclic olefinic carbon make mNHOs strong σ-donors and enable unique reactivity patterns.
This article highlights the recent advances in the field of mesoionic N-heterocyclic olefins (mNHOs). |
| doi_str_mv | 10.1039/d2dt01013e |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2022-06, Vol.51 (24), p.9191-9198 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_pubmed_primary_35642920 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alkenes Basicity Bonding strength Carbon |
| title | Recent advances of mesoionic N-heterocyclic olefins |
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