Transition-metal-free approaches to 2,3-diarylated indenones from 2-alkynylbenzaldehydes and phenols with tunable selectivity
The first transition-metal-free regioselective synthesis of 2,3-diarylindenones via tandem annulation of 2-alkynylbenzaldehydes with phenols is described. Two different modes of reaction controlled by electronic effects and temperature furnished either "non-rearranged" or "rearranged&...
Gespeichert in:
| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-04, Vol.58 (29), p.4592-4595 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4595 |
|---|---|
| container_issue | 29 |
| container_start_page | 4592 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 58 |
| creator | Yao, Tuanli Zhao, Shuaijing Liu, Tao Wu, Yuting Ma, Yanhui Li, Tao Qin, Xiangyang |
| description | The first transition-metal-free regioselective synthesis of 2,3-diarylindenones
via
tandem annulation of 2-alkynylbenzaldehydes with phenols is described. Two different modes of reaction controlled by electronic effects and temperature furnished either "non-rearranged" or "rearranged" indenones in high selectivity.
The first transition-metal-free synthesis of 2,3-diarylindenones with tunable selectivity
via
tandem annulation of 2-alkynylbenzaldehydes with phenols has been developed. |
| doi_str_mv | 10.1039/d2cc01324j |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmed_primary_35319038</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2642327025</sourcerecordid><originalsourceid>FETCH-LOGICAL-c267t-f506c5baf9b592476bb4f8b6df19d3485a8e988063764cecdfeb8b056ebba42f3</originalsourceid><addsrcrecordid>eNpd0c1rFDEYBvAgiq3Vi3cl4EXE0XzPzFHWr0rBSwVvQz7esLNmMmuSUUbo_96sWys0lwSeHy9JHoSeUvKGEt6_dcxaQjkTu3volHIlGim67_cPZ9k3LRfyBD3KeUfqorJ7iE645LQnvDtFV5dJxzyWcY7NBEWHxicArPf7NGu7hYzLjNlr3rhRpzXoAg6P0UGcY818mifMGh1-rHENBuIfHRxsV1czHR3ebysMGf8eyxaXJWoTAGcIYMv4ayzrY_TA65Dhyc1-hr59_HC5-dxcfP10vnl30Vim2tJ4SZSVRvveyJ6JVhkjfGeU87R3XHRSd9B3HVG8VcKCdR5MZ4hUYIwWzPMz9PI4t77q5wK5DNOYLYSgI8xLHpgSjLOWMFnpizt0Ny8p1tsdVKtoT4mo6tVR2TTnnMAP-zRO9YcGSoZDKcN7ttn8LeVLxc9vRi5mAndL_7VQwbMjSNnepv9b5dedjZNL</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2647619104</pqid></control><display><type>article</type><title>Transition-metal-free approaches to 2,3-diarylated indenones from 2-alkynylbenzaldehydes and phenols with tunable selectivity</title><source>MEDLINE</source><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Yao, Tuanli ; Zhao, Shuaijing ; Liu, Tao ; Wu, Yuting ; Ma, Yanhui ; Li, Tao ; Qin, Xiangyang</creator><creatorcontrib>Yao, Tuanli ; Zhao, Shuaijing ; Liu, Tao ; Wu, Yuting ; Ma, Yanhui ; Li, Tao ; Qin, Xiangyang</creatorcontrib><description>The first transition-metal-free regioselective synthesis of 2,3-diarylindenones
via
tandem annulation of 2-alkynylbenzaldehydes with phenols is described. Two different modes of reaction controlled by electronic effects and temperature furnished either "non-rearranged" or "rearranged" indenones in high selectivity.
The first transition-metal-free synthesis of 2,3-diarylindenones with tunable selectivity
via
tandem annulation of 2-alkynylbenzaldehydes with phenols has been developed.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d2cc01324j</identifier><identifier>PMID: 35319038</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Catalysis ; Chemical reactions ; Phenols ; Selectivity ; Transition Elements ; Transition metals</subject><ispartof>Chemical communications (Cambridge, England), 2022-04, Vol.58 (29), p.4592-4595</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c267t-f506c5baf9b592476bb4f8b6df19d3485a8e988063764cecdfeb8b056ebba42f3</citedby><cites>FETCH-LOGICAL-c267t-f506c5baf9b592476bb4f8b6df19d3485a8e988063764cecdfeb8b056ebba42f3</cites><orcidid>0000-0003-2905-6596</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27926,27927</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35319038$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yao, Tuanli</creatorcontrib><creatorcontrib>Zhao, Shuaijing</creatorcontrib><creatorcontrib>Liu, Tao</creatorcontrib><creatorcontrib>Wu, Yuting</creatorcontrib><creatorcontrib>Ma, Yanhui</creatorcontrib><creatorcontrib>Li, Tao</creatorcontrib><creatorcontrib>Qin, Xiangyang</creatorcontrib><title>Transition-metal-free approaches to 2,3-diarylated indenones from 2-alkynylbenzaldehydes and phenols with tunable selectivity</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>The first transition-metal-free regioselective synthesis of 2,3-diarylindenones
via
tandem annulation of 2-alkynylbenzaldehydes with phenols is described. Two different modes of reaction controlled by electronic effects and temperature furnished either "non-rearranged" or "rearranged" indenones in high selectivity.
The first transition-metal-free synthesis of 2,3-diarylindenones with tunable selectivity
via
tandem annulation of 2-alkynylbenzaldehydes with phenols has been developed.</description><subject>Catalysis</subject><subject>Chemical reactions</subject><subject>Phenols</subject><subject>Selectivity</subject><subject>Transition Elements</subject><subject>Transition metals</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpd0c1rFDEYBvAgiq3Vi3cl4EXE0XzPzFHWr0rBSwVvQz7esLNmMmuSUUbo_96sWys0lwSeHy9JHoSeUvKGEt6_dcxaQjkTu3volHIlGim67_cPZ9k3LRfyBD3KeUfqorJ7iE645LQnvDtFV5dJxzyWcY7NBEWHxicArPf7NGu7hYzLjNlr3rhRpzXoAg6P0UGcY818mifMGh1-rHENBuIfHRxsV1czHR3ebysMGf8eyxaXJWoTAGcIYMv4ayzrY_TA65Dhyc1-hr59_HC5-dxcfP10vnl30Vim2tJ4SZSVRvveyJ6JVhkjfGeU87R3XHRSd9B3HVG8VcKCdR5MZ4hUYIwWzPMz9PI4t77q5wK5DNOYLYSgI8xLHpgSjLOWMFnpizt0Ny8p1tsdVKtoT4mo6tVR2TTnnMAP-zRO9YcGSoZDKcN7ttn8LeVLxc9vRi5mAndL_7VQwbMjSNnepv9b5dedjZNL</recordid><startdate>20220407</startdate><enddate>20220407</enddate><creator>Yao, Tuanli</creator><creator>Zhao, Shuaijing</creator><creator>Liu, Tao</creator><creator>Wu, Yuting</creator><creator>Ma, Yanhui</creator><creator>Li, Tao</creator><creator>Qin, Xiangyang</creator><general>Royal Society of Chemistry</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2905-6596</orcidid></search><sort><creationdate>20220407</creationdate><title>Transition-metal-free approaches to 2,3-diarylated indenones from 2-alkynylbenzaldehydes and phenols with tunable selectivity</title><author>Yao, Tuanli ; Zhao, Shuaijing ; Liu, Tao ; Wu, Yuting ; Ma, Yanhui ; Li, Tao ; Qin, Xiangyang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c267t-f506c5baf9b592476bb4f8b6df19d3485a8e988063764cecdfeb8b056ebba42f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Catalysis</topic><topic>Chemical reactions</topic><topic>Phenols</topic><topic>Selectivity</topic><topic>Transition Elements</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yao, Tuanli</creatorcontrib><creatorcontrib>Zhao, Shuaijing</creatorcontrib><creatorcontrib>Liu, Tao</creatorcontrib><creatorcontrib>Wu, Yuting</creatorcontrib><creatorcontrib>Ma, Yanhui</creatorcontrib><creatorcontrib>Li, Tao</creatorcontrib><creatorcontrib>Qin, Xiangyang</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yao, Tuanli</au><au>Zhao, Shuaijing</au><au>Liu, Tao</au><au>Wu, Yuting</au><au>Ma, Yanhui</au><au>Li, Tao</au><au>Qin, Xiangyang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transition-metal-free approaches to 2,3-diarylated indenones from 2-alkynylbenzaldehydes and phenols with tunable selectivity</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2022-04-07</date><risdate>2022</risdate><volume>58</volume><issue>29</issue><spage>4592</spage><epage>4595</epage><pages>4592-4595</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The first transition-metal-free regioselective synthesis of 2,3-diarylindenones
via
tandem annulation of 2-alkynylbenzaldehydes with phenols is described. Two different modes of reaction controlled by electronic effects and temperature furnished either "non-rearranged" or "rearranged" indenones in high selectivity.
The first transition-metal-free synthesis of 2,3-diarylindenones with tunable selectivity
via
tandem annulation of 2-alkynylbenzaldehydes with phenols has been developed.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35319038</pmid><doi>10.1039/d2cc01324j</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-2905-6596</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2022-04, Vol.58 (29), p.4592-4595 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_pubmed_primary_35319038 |
| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Catalysis Chemical reactions Phenols Selectivity Transition Elements Transition metals |
| title | Transition-metal-free approaches to 2,3-diarylated indenones from 2-alkynylbenzaldehydes and phenols with tunable selectivity |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-18T07%3A50%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Transition-metal-free%20approaches%20to%202,3-diarylated%20indenones%20from%202-alkynylbenzaldehydes%20and%20phenols%20with%20tunable%20selectivity&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Yao,%20Tuanli&rft.date=2022-04-07&rft.volume=58&rft.issue=29&rft.spage=4592&rft.epage=4595&rft.pages=4592-4595&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/d2cc01324j&rft_dat=%3Cproquest_pubme%3E2642327025%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2647619104&rft_id=info:pmid/35319038&rfr_iscdi=true |