Characterization of a Triplet Vinylidene

Singlet vinylidenes (R2CC:) are proposed as intermediates in a series of organic reactions, and very few have been studied by matrix isolation or gas-phase spectroscopy. Triplet vinylidenes, however, featuring two unpaired electrons at a monosubstituted carbon atom are thus far only predicted as el...

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Veröffentlicht in:Journal of the American Chemical Society 2021-12, Vol.143 (50), p.21410-21415
Hauptverfasser: Kutin, Yury, Reitz, Justus, Antoni, Patrick W, Savitsky, Anton, Pantazis, Dimitrios A, Kasanmascheff, Müge, Hansmann, Max M
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Sprache:eng
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