Metal-semiconductor heterostructures for surface-enhanced Raman scattering: synergistic contribution of plasmons and charge transfer

After 45 years of its first observation, surface-enhanced Raman spectroscopy (SERS) has become an ultrasensitive tool applied in chemical analysis, materials science, and biomedical research. SERS-active nanomaterials, such as noble metals, transition metals, and semiconductors, have undergone exten...

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Veröffentlicht in:Materials horizons 2021-02, Vol.8 (2), p.37-382
Hauptverfasser: Liu, Yawen, Ma, Hao, Han, Xiao Xia, Zhao, Bing
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Ma, Hao
Han, Xiao Xia
Zhao, Bing
description After 45 years of its first observation, surface-enhanced Raman spectroscopy (SERS) has become an ultrasensitive tool applied in chemical analysis, materials science, and biomedical research. SERS-active nanomaterials, such as noble metals, transition metals, and semiconductors, have undergone extensive development. The hybridization of semiconductors with plasmonic metal nanomaterials is highly effective in boosting light harvesting and conversion, which enables the rapid growth of metal-semiconductor hybrid nanostructures in SERS-based research fields. With the combination of the unique photoelectric properties and giant SERS signals attributed to the synergistic contribution of plasmons and change transfer (CT), metal-semiconductor heterostructures allow diverse and novel applications of SERS in CT investigations for the rational design of photovoltaic devices and ultrasensitive chemical or biological sensing. In this review, we specifically discuss SERS-active metal-semiconductor heterostructures including their building blocks, enhancement mechanisms, and applications. Moreover, we highlight the current challenges and opportunities for future research in this field based on our recent studies and other related research. SERS on metal-semiconductor heterostructures including their building blocks, enhancement mechanisms and applications was reviewed. The synergistic contribution of plasmons and charge transfer is highlighted.
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source MEDLINE; Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Biomedical materials
Charge transfer
Chemical analysis
Heterostructures
Materials science
Metals
Nanomaterials
Nanostructures
Noble metals
Photoelectric effect
Photoelectricity
Photovoltaic cells
Plasmons
Raman spectra
Raman spectroscopy
Semiconductors
Spectrum Analysis, Raman
Transition metals
title Metal-semiconductor heterostructures for surface-enhanced Raman scattering: synergistic contribution of plasmons and charge transfer
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