Use of Green Solvents in Metallaphotoredox Cross-Electrophile Coupling Reactions Utilizing a Lipophilic Modified Dual Ir/Ni Catalyst System
Facilitating photoredox coupling reactions in process-friendly green solvents was achieved by the successful application of a dual Ir/Ni catalyst system with enhanced solubility properties. These photochemical reactions (specifically Br-Br sp(2)-sp(3) cross electrophile coupling) are reported in a h...
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| Veröffentlicht in: | Journal of organic chemistry 2021-12, Vol.86 (23), p.17428-17436 |
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| container_end_page | 17436 |
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| container_issue | 23 |
| container_start_page | 17428 |
| container_title | Journal of organic chemistry |
| container_volume | 86 |
| creator | Delgado, Pete Glass, Raoul J. Geraci, Gina Duvadie, Rohit Majumdar, Dyuti Robinson, Richard Elmaarouf, Imran Mikus, Malte Tan, Kian L. |
| description | Facilitating photoredox coupling reactions in process-friendly green solvents was achieved by the successful application of a dual Ir/Ni catalyst system with enhanced solubility properties. These photochemical reactions (specifically Br-Br sp(2)-sp(3) cross electrophile coupling) are reported in a head to head comparison to the standard di-t-Bu bipyridine ligand Ir/Ni catalyst system. This presentation highlights the benefits of altering the solubility properties of the ligands used in the Ir/Ni dual catalyst. |
| doi_str_mv | 10.1021/acs.joc.1c02013 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0022-3263 |
| ispartof | Journal of organic chemistry, 2021-12, Vol.86 (23), p.17428-17436 |
| issn | 0022-3263 1520-6904 |
| language | eng |
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| source | MEDLINE; ACS Publications; Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /> |
| subjects | Catalysis Chemistry Chemistry, Organic Ligands Nickel Oxidation-Reduction Physical Sciences Science & Technology Solvents |
| title | Use of Green Solvents in Metallaphotoredox Cross-Electrophile Coupling Reactions Utilizing a Lipophilic Modified Dual Ir/Ni Catalyst System |
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