Stereoselective synthesis of new pyran-dioxane based polycycles from glycal derived vinyl epoxide

Chiral heteropolycyclic structures are widespread in compounds of high pharmaceutical relevance. In particular, linear fused pyran-dioxane based polycycles can be found in several naturally occurring molecules, and among them, cardiac glycosides and antibiotic spectinomycin are characterized by a ci...

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Veröffentlicht in:	Organic & biomolecular chemistry 2021-11, Vol.19 (42), p.919-9198
Hauptverfasser:	Iacopini, Dalila, Barbini, Gabriele, Favero, Lucilla, Pineschi, Mauro, Di Pietro, Sebastiano, Di Bussolo, Valeria
Format:	Artikel
Sprache:	eng
Schlagworte:	Antibiotics Cardiac glycosides Computer applications Cyclohexane Glycosides Glycosylation Natural products NMR Nuclear magnetic resonance Spectinomycin Stereochemistry Stereoselectivity Substrates Synthesis Tricycles
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