Fluorescein Based Three-channel Probe for the Selective and Sensitive Detection of CO 3 2- Ions in an Aqueous Environment and Real Water Samples
We have constructed a novel fluorescein-based fluorescent chemosensor, FL-In, functionalised with an indole moiety and capable of sensing by both the optical "turn-on" and electrochemical detection of carbonate ions (CO ) in aqueous media. The probe exhibits excellent selectivity and a low...
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| Veröffentlicht in: | Journal of fluorescence 2021-11, Vol.31 (6), p.1617 |
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| container_issue | 6 |
| container_start_page | 1617 |
| container_title | Journal of fluorescence |
| container_volume | 31 |
| creator | Karakuş, Erman Erdemir, Eda Suna, Garen Liv, Lokman Gunduz, Simay Can, Şevval Arzu |
| description | We have constructed a novel fluorescein-based fluorescent chemosensor, FL-In, functionalised with an indole moiety and capable of sensing by both the optical "turn-on" and electrochemical detection of carbonate ions (CO
) in aqueous media. The probe exhibits excellent selectivity and a low detection limit (0.27 µM) regarding carbonate ions by a possible coordination and hydrolysis reaction mechanism. The developed probe successfully detected CO
ions in different samples of water. Also, in a simple filter paper experiment, we documented its ability to allow the monitoring of CO
with the naked eye. |
| doi_str_mv | 10.1007/s10895-021-02779-0 |
| format | Article |
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) in aqueous media. The probe exhibits excellent selectivity and a low detection limit (0.27 µM) regarding carbonate ions by a possible coordination and hydrolysis reaction mechanism. The developed probe successfully detected CO
ions in different samples of water. Also, in a simple filter paper experiment, we documented its ability to allow the monitoring of CO
with the naked eye.</description><identifier>EISSN: 1573-4994</identifier><identifier>DOI: 10.1007/s10895-021-02779-0</identifier><identifier>PMID: 34357494</identifier><language>eng</language><publisher>Netherlands</publisher><subject>Carbonates - analysis ; Drinking Water - analysis ; Electrochemical Techniques ; Fluorescent Dyes - chemical synthesis ; Fluorescent Dyes - chemistry ; Ions - analysis ; Molecular Structure ; Water Pollutants, Chemical - chemistry</subject><ispartof>Journal of fluorescence, 2021-11, Vol.31 (6), p.1617</ispartof><rights>2021. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-2691-8704</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34357494$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Karakuş, Erman</creatorcontrib><creatorcontrib>Erdemir, Eda</creatorcontrib><creatorcontrib>Suna, Garen</creatorcontrib><creatorcontrib>Liv, Lokman</creatorcontrib><creatorcontrib>Gunduz, Simay</creatorcontrib><creatorcontrib>Can, Şevval Arzu</creatorcontrib><title>Fluorescein Based Three-channel Probe for the Selective and Sensitive Detection of CO 3 2- Ions in an Aqueous Environment and Real Water Samples</title><title>Journal of fluorescence</title><addtitle>J Fluoresc</addtitle><description>We have constructed a novel fluorescein-based fluorescent chemosensor, FL-In, functionalised with an indole moiety and capable of sensing by both the optical "turn-on" and electrochemical detection of carbonate ions (CO
) in aqueous media. The probe exhibits excellent selectivity and a low detection limit (0.27 µM) regarding carbonate ions by a possible coordination and hydrolysis reaction mechanism. The developed probe successfully detected CO
ions in different samples of water. Also, in a simple filter paper experiment, we documented its ability to allow the monitoring of CO
with the naked eye.</description><subject>Carbonates - analysis</subject><subject>Drinking Water - analysis</subject><subject>Electrochemical Techniques</subject><subject>Fluorescent Dyes - chemical synthesis</subject><subject>Fluorescent Dyes - chemistry</subject><subject>Ions - analysis</subject><subject>Molecular Structure</subject><subject>Water Pollutants, Chemical - chemistry</subject><issn>1573-4994</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFj8FKAzEYhIMgtlZfwIP8LxBNmiy7OWptqSelLXgs6e6_bCT7Z012C76Fj-xa9OxhGGYYPhjGbqS4k0Lk90mKwmRczOWoPDdcnLGpzHLFtTF6wi5TehdCmEIXF2yitMpybfSUfa38ECKmEh3Bo01Ywa6JiLxsLBF6eI3hgFCHCH2DsEWPZe-OCJaqMVFyp_SE_U8fCEINixdQMOfwHCjBiLUEDx8DhiHBko4uBmqR-hNhg9bDm-0xwta2ncd0xc5r6xNe__qM3a6Wu8Wad8OhxWrfRdfa-Ln_u6D-HXwDScRXZA</recordid><startdate>202111</startdate><enddate>202111</enddate><creator>Karakuş, Erman</creator><creator>Erdemir, Eda</creator><creator>Suna, Garen</creator><creator>Liv, Lokman</creator><creator>Gunduz, Simay</creator><creator>Can, Şevval Arzu</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><orcidid>https://orcid.org/0000-0002-2691-8704</orcidid></search><sort><creationdate>202111</creationdate><title>Fluorescein Based Three-channel Probe for the Selective and Sensitive Detection of CO 3 2- Ions in an Aqueous Environment and Real Water Samples</title><author>Karakuş, Erman ; Erdemir, Eda ; Suna, Garen ; Liv, Lokman ; Gunduz, Simay ; Can, Şevval Arzu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_343574943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Carbonates - analysis</topic><topic>Drinking Water - analysis</topic><topic>Electrochemical Techniques</topic><topic>Fluorescent Dyes - chemical synthesis</topic><topic>Fluorescent Dyes - chemistry</topic><topic>Ions - analysis</topic><topic>Molecular Structure</topic><topic>Water Pollutants, Chemical - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karakuş, Erman</creatorcontrib><creatorcontrib>Erdemir, Eda</creatorcontrib><creatorcontrib>Suna, Garen</creatorcontrib><creatorcontrib>Liv, Lokman</creatorcontrib><creatorcontrib>Gunduz, Simay</creatorcontrib><creatorcontrib>Can, Şevval Arzu</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><jtitle>Journal of fluorescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karakuş, Erman</au><au>Erdemir, Eda</au><au>Suna, Garen</au><au>Liv, Lokman</au><au>Gunduz, Simay</au><au>Can, Şevval Arzu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fluorescein Based Three-channel Probe for the Selective and Sensitive Detection of CO 3 2- Ions in an Aqueous Environment and Real Water Samples</atitle><jtitle>Journal of fluorescence</jtitle><addtitle>J Fluoresc</addtitle><date>2021-11</date><risdate>2021</risdate><volume>31</volume><issue>6</issue><spage>1617</spage><pages>1617-</pages><eissn>1573-4994</eissn><abstract>We have constructed a novel fluorescein-based fluorescent chemosensor, FL-In, functionalised with an indole moiety and capable of sensing by both the optical "turn-on" and electrochemical detection of carbonate ions (CO
) in aqueous media. The probe exhibits excellent selectivity and a low detection limit (0.27 µM) regarding carbonate ions by a possible coordination and hydrolysis reaction mechanism. The developed probe successfully detected CO
ions in different samples of water. Also, in a simple filter paper experiment, we documented its ability to allow the monitoring of CO
with the naked eye.</abstract><cop>Netherlands</cop><pmid>34357494</pmid><doi>10.1007/s10895-021-02779-0</doi><orcidid>https://orcid.org/0000-0002-2691-8704</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 1573-4994 |
| ispartof | Journal of fluorescence, 2021-11, Vol.31 (6), p.1617 |
| issn | 1573-4994 |
| language | eng |
| recordid | cdi_pubmed_primary_34357494 |
| source | MEDLINE; SpringerLink Journals (MCLS) |
| subjects | Carbonates - analysis Drinking Water - analysis Electrochemical Techniques Fluorescent Dyes - chemical synthesis Fluorescent Dyes - chemistry Ions - analysis Molecular Structure Water Pollutants, Chemical - chemistry |
| title | Fluorescein Based Three-channel Probe for the Selective and Sensitive Detection of CO 3 2- Ions in an Aqueous Environment and Real Water Samples |
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