Synthesis, C-H bond functionalisation and cycloadditions of 6-styryl-1,2-oxathiine 2,2-dioxides

A series of 6-styryl-1,2-oxathiine 2,2-dioxides have been efficiently obtained by a two-step protocol from readily available (1 E ,4 E )-1-(dimethylamino)-5-arylpenta-1,4-dien-3-ones involving a regioselective sulfene addition and subsequent Cope elimination. Pd-Mediated direct C-H bond functionalis...

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Veröffentlicht in:	Organic & biomolecular chemistry 2021-07, Vol.19 (29), p.6431-6446
Hauptverfasser:	Gabbutt, Christopher D, Heron, B. Mark, Lilly, Thomas, Ogwang, Ochola W, Zonidis, Dimitrios
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Bromination Cross coupling Cycloaddition Fluorides Hydrogen bonds Isomerization Silica Silicon dioxide Substitutes
Online-Zugang:	Volltext
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