Modulating the stacking modes of nanosized metal-organic frameworks by morphology engineering for isomer separation
Modulating different stacking modes of nanoscale metal-organic frameworks (MOFs) introduces different properties and functionalities but remains a great challenge. Here, we describe a morphology engineering method to modulate the stacking modes of nanoscale NU-901. The nanoscale NU-901 is stacked th...
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| Veröffentlicht in: | Chemical science (Cambridge) 2021-02, Vol.12 (11), p.414-411 |
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| creator | Xu, Ming Meng, Sha-Sha Cai, Peiyu Tang, Wen-Qi Yin, Yun-Dong Powell, Joshua A Zhou, Hong-Cai Gu, Zhi-Yuan |
| description | Modulating different stacking modes of nanoscale metal-organic frameworks (MOFs) introduces different properties and functionalities but remains a great challenge. Here, we describe a morphology engineering method to modulate the stacking modes of nanoscale NU-901. The nanoscale NU-901 is stacked through solvent removal after one-pot solvothermal synthesis, in which different morphologies from nanosheets (NS) to interpenetrated nanosheets (I-NS) and nanoparticles (NP) were obtained successfully. The stacked NU-901-NS, NU-901-I-NS, and NU-901-NP exhibited relatively aligned stacking, random stacking, and close packing, respectively. The three stacked nanoscale NU-901 exhibited different separation abilities and all showed better performance than bulk phase NU-901. Our work provides a new morphology engineering route for the modulation of the stacking modes of nano-sized MOFs and improves the separation abilities of MOFs.
A morphology engineering method was utilized to modulate the stacking modes of three nano-NU-901 materials, leading to different separation abilities for isomers. |
| doi_str_mv | 10.1039/d0sc06747d |
| format | Article |
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A morphology engineering method was utilized to modulate the stacking modes of three nano-NU-901 materials, leading to different separation abilities for isomers.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/d0sc06747d</identifier><identifier>PMID: 34163681</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chemistry ; Metal-organic frameworks ; Morphology ; Nanoparticles ; Nanostructure ; Separation ; Stacking</subject><ispartof>Chemical science (Cambridge), 2021-02, Vol.12 (11), p.414-411</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2021</rights><rights>This journal is © The Royal Society of Chemistry 2021 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c428t-b94eb1c13ee6a941d1b8591911a637c54c783bc3dac4f5d58740dd57f6583d7b3</citedby><cites>FETCH-LOGICAL-c428t-b94eb1c13ee6a941d1b8591911a637c54c783bc3dac4f5d58740dd57f6583d7b3</cites><orcidid>0000-0002-6245-4759 ; 0000-0002-9029-3788</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179526/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179526/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34163681$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Ming</creatorcontrib><creatorcontrib>Meng, Sha-Sha</creatorcontrib><creatorcontrib>Cai, Peiyu</creatorcontrib><creatorcontrib>Tang, Wen-Qi</creatorcontrib><creatorcontrib>Yin, Yun-Dong</creatorcontrib><creatorcontrib>Powell, Joshua A</creatorcontrib><creatorcontrib>Zhou, Hong-Cai</creatorcontrib><creatorcontrib>Gu, Zhi-Yuan</creatorcontrib><title>Modulating the stacking modes of nanosized metal-organic frameworks by morphology engineering for isomer separation</title><title>Chemical science (Cambridge)</title><addtitle>Chem Sci</addtitle><description>Modulating different stacking modes of nanoscale metal-organic frameworks (MOFs) introduces different properties and functionalities but remains a great challenge. Here, we describe a morphology engineering method to modulate the stacking modes of nanoscale NU-901. The nanoscale NU-901 is stacked through solvent removal after one-pot solvothermal synthesis, in which different morphologies from nanosheets (NS) to interpenetrated nanosheets (I-NS) and nanoparticles (NP) were obtained successfully. The stacked NU-901-NS, NU-901-I-NS, and NU-901-NP exhibited relatively aligned stacking, random stacking, and close packing, respectively. The three stacked nanoscale NU-901 exhibited different separation abilities and all showed better performance than bulk phase NU-901. Our work provides a new morphology engineering route for the modulation of the stacking modes of nano-sized MOFs and improves the separation abilities of MOFs.
A morphology engineering method was utilized to modulate the stacking modes of three nano-NU-901 materials, leading to different separation abilities for isomers.</description><subject>Chemistry</subject><subject>Metal-organic frameworks</subject><subject>Morphology</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>Separation</subject><subject>Stacking</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpd0s9vFCEUB3BiNLapvXjXkHgxJqMw_Jq5mJittk3aeFDPhIE3s7QzsMKMZv3rZbt1rXIBwidfHnkg9JySt5Sw9p0j2RKpuHKP0HFNOK2kYO3jw7omR-g05xtSBmNU1OopOmKcSiYbeozydXTLaGYfBjyvAefZ2NvdZooOMo49DibE7H-BwxPMZqxiGkzwFvfJTPAzptuMu23habOOYxy2GMLgA0DapfQxYZ_jBAln2JhULorhGXrSmzHD6f18gr59-vh1dVFdfT6_XH24qiyvm7nqWg4dtZQBSNNy6mjXiJa2lBrJlBXcqoZ1ljljeS-caBQnzgnVS9Ewpzp2gt7vczdLN4GzEOZkRr1JfjJpq6Px-t-T4Nd6iD90Q1UralkCXt8HpPh9gTzryWcL42gCxCXrWnDeqKJFoa_-ozdxSaE8ryjCFeW1VEW92SubYs4J-kMxlOhdO_UZ-bK6a-dZwS8fln-gf5pXwIs9SNkeTv_-B_YbQhanWA</recordid><startdate>20210203</startdate><enddate>20210203</enddate><creator>Xu, Ming</creator><creator>Meng, Sha-Sha</creator><creator>Cai, Peiyu</creator><creator>Tang, Wen-Qi</creator><creator>Yin, Yun-Dong</creator><creator>Powell, Joshua A</creator><creator>Zhou, Hong-Cai</creator><creator>Gu, Zhi-Yuan</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-6245-4759</orcidid><orcidid>https://orcid.org/0000-0002-9029-3788</orcidid></search><sort><creationdate>20210203</creationdate><title>Modulating the stacking modes of nanosized metal-organic frameworks by morphology engineering for isomer separation</title><author>Xu, Ming ; Meng, Sha-Sha ; Cai, Peiyu ; Tang, Wen-Qi ; Yin, Yun-Dong ; Powell, Joshua A ; Zhou, Hong-Cai ; Gu, Zhi-Yuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c428t-b94eb1c13ee6a941d1b8591911a637c54c783bc3dac4f5d58740dd57f6583d7b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>Metal-organic frameworks</topic><topic>Morphology</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>Separation</topic><topic>Stacking</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Ming</creatorcontrib><creatorcontrib>Meng, Sha-Sha</creatorcontrib><creatorcontrib>Cai, Peiyu</creatorcontrib><creatorcontrib>Tang, Wen-Qi</creatorcontrib><creatorcontrib>Yin, Yun-Dong</creatorcontrib><creatorcontrib>Powell, Joshua A</creatorcontrib><creatorcontrib>Zhou, Hong-Cai</creatorcontrib><creatorcontrib>Gu, Zhi-Yuan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Ming</au><au>Meng, Sha-Sha</au><au>Cai, Peiyu</au><au>Tang, Wen-Qi</au><au>Yin, Yun-Dong</au><au>Powell, Joshua A</au><au>Zhou, Hong-Cai</au><au>Gu, Zhi-Yuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modulating the stacking modes of nanosized metal-organic frameworks by morphology engineering for isomer separation</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2021-02-03</date><risdate>2021</risdate><volume>12</volume><issue>11</issue><spage>414</spage><epage>411</epage><pages>414-411</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Modulating different stacking modes of nanoscale metal-organic frameworks (MOFs) introduces different properties and functionalities but remains a great challenge. Here, we describe a morphology engineering method to modulate the stacking modes of nanoscale NU-901. The nanoscale NU-901 is stacked through solvent removal after one-pot solvothermal synthesis, in which different morphologies from nanosheets (NS) to interpenetrated nanosheets (I-NS) and nanoparticles (NP) were obtained successfully. The stacked NU-901-NS, NU-901-I-NS, and NU-901-NP exhibited relatively aligned stacking, random stacking, and close packing, respectively. The three stacked nanoscale NU-901 exhibited different separation abilities and all showed better performance than bulk phase NU-901. Our work provides a new morphology engineering route for the modulation of the stacking modes of nano-sized MOFs and improves the separation abilities of MOFs.
A morphology engineering method was utilized to modulate the stacking modes of three nano-NU-901 materials, leading to different separation abilities for isomers.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>34163681</pmid><doi>10.1039/d0sc06747d</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-6245-4759</orcidid><orcidid>https://orcid.org/0000-0002-9029-3788</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Chemistry Metal-organic frameworks Morphology Nanoparticles Nanostructure Separation Stacking |
| title | Modulating the stacking modes of nanosized metal-organic frameworks by morphology engineering for isomer separation |
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