Formic acid dehydrogenation over PdNi alloys supported on N-doped carbon: synergistic effect of Pd-Ni alloying on hydrogen release

Bimetallic Pd 1 Ni x alloys supported on nitrogen-doped carbon (Pd 1 Ni x /N-C, x = 0.37, 1.3 and 3.6) exhibit higher activities than Pd/N-C towards dehydrogenation of formic acid (HCO 2 H, FA). Density functional theory (DFT) calculations provided electronic and atomic structures, energetics and re...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2021-05, Vol.23 (19), p.11515-11527
Hauptverfasser:	Tamarany, Rizcky, Shin, Dong Yun, Kang, Sukho, Jeong, Hyangsoo, Kim, Joohoon, Kim, Jun, Yoon, Chang Won, Lim, Dong-Hee
Format:	Artikel
Sprache:	eng
Schlagworte:	Alloying effects Bimetals Carbon Dehydrogenation Density functional theory Density of states Formic acid Nitrogen Oxygen atoms Synergistic effect
Online-Zugang:	Volltext
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