Fast-Response Colorimetric UVC Sensor Made of a Ga 2 O 3 Photocatalyst with a Hole Scavenger
A fast-response colorimetric ultraviolet-C (UVC) sensor was demonstrated using a gallium oxide (Ga O ) photocatalyst with small amounts of triethanolamine (TEOA) in methylene blue (MB) solutions and a conventional RGB photodetector. The color of the MB solution changed upon UVC exposure, which was o...
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Veröffentlicht in: | Sensors (Basel, Switzerland) Switzerland), 2021-01, Vol.21 (2) |
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creator | Ryou, Heejoong Kim, Sunjae Shin, Myunghun Cho, Junsang Hwang, Wan Sik |
description | A fast-response colorimetric ultraviolet-C (UVC) sensor was demonstrated using a gallium oxide (Ga
O
) photocatalyst with small amounts of triethanolamine (TEOA) in methylene blue (MB) solutions and a conventional RGB photodetector. The color of the MB solution changed upon UVC exposure, which was observed using an in situ RGB photodetector. Thereby, the UVC exposure was numerically quantified as an MB reduction rate with the
value of the photodetector, which was linearly correlated with the measured spectral absorbance using a UV-Vis spectrophotometer. Small amount of TEOA in the MB solution served as a hole scavenger, which resulted in fast MB color changes due to the enhanced charge separation. However, excessive TEOA over 5 wt.% started to block the catalytical active site on the surface of Ga
O
, prohibiting the chemical reaction between the MB molecules and catalytic sites. The proposed colorimetric UVC sensor could monitor the detrimental UVC radiation with high responsivity at a low cost. |
doi_str_mv | 10.3390/s21020387 |
format | Article |
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O
) photocatalyst with small amounts of triethanolamine (TEOA) in methylene blue (MB) solutions and a conventional RGB photodetector. The color of the MB solution changed upon UVC exposure, which was observed using an in situ RGB photodetector. Thereby, the UVC exposure was numerically quantified as an MB reduction rate with the
value of the photodetector, which was linearly correlated with the measured spectral absorbance using a UV-Vis spectrophotometer. Small amount of TEOA in the MB solution served as a hole scavenger, which resulted in fast MB color changes due to the enhanced charge separation. However, excessive TEOA over 5 wt.% started to block the catalytical active site on the surface of Ga
O
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O
) photocatalyst with small amounts of triethanolamine (TEOA) in methylene blue (MB) solutions and a conventional RGB photodetector. The color of the MB solution changed upon UVC exposure, which was observed using an in situ RGB photodetector. Thereby, the UVC exposure was numerically quantified as an MB reduction rate with the
value of the photodetector, which was linearly correlated with the measured spectral absorbance using a UV-Vis spectrophotometer. Small amount of TEOA in the MB solution served as a hole scavenger, which resulted in fast MB color changes due to the enhanced charge separation. However, excessive TEOA over 5 wt.% started to block the catalytical active site on the surface of Ga
O
, prohibiting the chemical reaction between the MB molecules and catalytic sites. The proposed colorimetric UVC sensor could monitor the detrimental UVC radiation with high responsivity at a low cost.</description><issn>1424-8220</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFjsFqwkAURQehGGtd-APyfiB1Mi9gXAc1G1GM7aogz_g0kZgJ86aV_L0u2nVXd3EOnKvUONLviHM9FRNpozGZ9dQgik0cJsboQL2KXLU2iJj0VYAYm3kyiwfqa0niwx1LaxthSG1tXXVj76oCPj5TyLkR62BNJwZ7BoIVgYENIGxL621BnupOPNwrXz5pZmuGvKAfbi7s3tTLmWrh0e8O1WS52KdZ2H4fb3w6tM8Uue7wdwf_FR4QrUI_</recordid><startdate>20210108</startdate><enddate>20210108</enddate><creator>Ryou, Heejoong</creator><creator>Kim, Sunjae</creator><creator>Shin, Myunghun</creator><creator>Cho, Junsang</creator><creator>Hwang, Wan Sik</creator><scope>NPM</scope><orcidid>https://orcid.org/0000-0003-4211-4113</orcidid><orcidid>https://orcid.org/0000-0002-0060-9348</orcidid><orcidid>https://orcid.org/0000-0003-1821-2186</orcidid></search><sort><creationdate>20210108</creationdate><title>Fast-Response Colorimetric UVC Sensor Made of a Ga 2 O 3 Photocatalyst with a Hole Scavenger</title><author>Ryou, Heejoong ; Kim, Sunjae ; Shin, Myunghun ; Cho, Junsang ; Hwang, Wan Sik</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_334298743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ryou, Heejoong</creatorcontrib><creatorcontrib>Kim, Sunjae</creatorcontrib><creatorcontrib>Shin, Myunghun</creatorcontrib><creatorcontrib>Cho, Junsang</creatorcontrib><creatorcontrib>Hwang, Wan Sik</creatorcontrib><collection>PubMed</collection><jtitle>Sensors (Basel, Switzerland)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ryou, Heejoong</au><au>Kim, Sunjae</au><au>Shin, Myunghun</au><au>Cho, Junsang</au><au>Hwang, Wan Sik</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fast-Response Colorimetric UVC Sensor Made of a Ga 2 O 3 Photocatalyst with a Hole Scavenger</atitle><jtitle>Sensors (Basel, Switzerland)</jtitle><addtitle>Sensors (Basel)</addtitle><date>2021-01-08</date><risdate>2021</risdate><volume>21</volume><issue>2</issue><eissn>1424-8220</eissn><abstract>A fast-response colorimetric ultraviolet-C (UVC) sensor was demonstrated using a gallium oxide (Ga
O
) photocatalyst with small amounts of triethanolamine (TEOA) in methylene blue (MB) solutions and a conventional RGB photodetector. The color of the MB solution changed upon UVC exposure, which was observed using an in situ RGB photodetector. Thereby, the UVC exposure was numerically quantified as an MB reduction rate with the
value of the photodetector, which was linearly correlated with the measured spectral absorbance using a UV-Vis spectrophotometer. Small amount of TEOA in the MB solution served as a hole scavenger, which resulted in fast MB color changes due to the enhanced charge separation. However, excessive TEOA over 5 wt.% started to block the catalytical active site on the surface of Ga
O
, prohibiting the chemical reaction between the MB molecules and catalytic sites. The proposed colorimetric UVC sensor could monitor the detrimental UVC radiation with high responsivity at a low cost.</abstract><cop>Switzerland</cop><pmid>33429874</pmid><doi>10.3390/s21020387</doi><orcidid>https://orcid.org/0000-0003-4211-4113</orcidid><orcidid>https://orcid.org/0000-0002-0060-9348</orcidid><orcidid>https://orcid.org/0000-0003-1821-2186</orcidid></addata></record> |
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title | Fast-Response Colorimetric UVC Sensor Made of a Ga 2 O 3 Photocatalyst with a Hole Scavenger |
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