Histidine orientation in artificial peroxidase regioisomers as determined by paramagnetic NMR shifts

Fe-Mimochrome VI*a is a synthetic peroxidase and peroxygenase, featuring two different peptides that are covalently-linked to deuteroheme. To perform a systematic structure/function correlation, we purposely shortened the distance between the distal peptide and the heme, allowing for the separation...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2021-02, Vol.57 (8), p.99-993
Hauptverfasser:	Maglio, Ornella, Chino, Marco, Vicari, Claudia, Pavone, Vincenzo, Louro, Ricardo O, Lombardi, Angela
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry, Multidisciplinary Histidine Ligands NMR Nuclear magnetic resonance Orientation Peptides Peroxidase Physical Sciences Science & Technology
Online-Zugang:	Volltext
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