Reactivation of sulfide-protected [FeFe] hydrogenase in a redox-active hydrogel

[FeFe] hydrogenases are highly active hydrogen conversion catalysts but are notoriously sensitive to oxidative damage. Redox hydrogels have been used for protecting hydrogenases from both high potential inactivation and oxygen inactivation under turnover conditions. However, [FeFe] hydrogenase conta...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2020-09, Vol.56 (69), p.9958-9961
Hauptverfasser:	Oughli, Alaa A, Hardt, Steffen, Rüdiger, Olaf, Birrell, James A, Plumeré, Nicolas
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Biocatalysis Deactivation Desulfovibrio desulfuricans - enzymology Enzyme Stability Enzymes Hydrogels Hydrogels - chemistry Hydrogenase Hydrogenase - chemistry Hydrogenase - metabolism Oxidation-Reduction Oxygen Oxygen - chemistry Sulfides - chemistry
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