Stereoselective Access to Fully Substituted Aldehyde Silyl Enol Ethers by Iridium-Catalyzed Alkene Isomerization

In the presence of 1 mol% of an Ir-based catalyst, simple allylic silyl ethers are transformed into valuable, fully substituted aldehyde-derived silyl enol ethers. Importantly, by judicious choice of substrate, either of the two possible stereoisomers of a given enolate derivative is accessible with...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-05
Hauptverfasser:	Marek, Ilan, Massad, Itai, Sommer, Heiko
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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