Spin crossover in 2D iron() phthalazine cyanometallic complexes

Two new 2D spin-crossover (SCO) analogues of Hofmann clathrates of composition [Fe(phth) 2 M II (CN) 4 ] (where phth = phthalazine; M II = Pd, Pt) have been synthesized and their structures and switchable behaviour have been characterized. Single-crystal X-ray analysis reveals that the Pt and Pd der...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-04, Vol.49 (16), p.532-5311
Hauptverfasser:	Hiiuk, Volodymyr M, Shova, Sergiu, Rotaru, Aurelian, Golub, Alexander A, Fritsky, Igor O, Gural'skiy, Il'ya A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry, Inorganic & Nuclear Clathrates Coordination compounds Crossovers Crystal structure Crystallography Derivatives Equivalence Hysteresis loops Infrared spectroscopy Iron Ligands Magnetic permeability Optical measurement Palladium Physical Sciences Platinum Raman spectroscopy Science & Technology Single crystals Temperature dependence X ray analysis
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