The first hydride-Meisenheimer adduct of electron-deficient 3-nitronaphthalimide: application to colorimetric borohydride determination

The first hydride-Meisenheimer adduct of 3-nitronaphthalimide was used for the colorimetric borohydride assay. To explain the regioselectivity of the adduct, the reaction enthalpies of the two most plausible Meisenheimer adducts were obtained via computational calculation. Using the adduct formation...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2019-09, Vol.55 (76), p.11398-1141
Hauptverfasser:	Choi, Myung Gil, Kim, Na Yeong, Lee, Yu Jeong, Ahn, Sangdoo, Chang, Suk-Kyu
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Borohydrides Colorimetry Enthalpy Hydrides Mathematical analysis NMR Nuclear magnetic resonance Reagents Regioselectivity
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container_title	Chemical communications (Cambridge, England)
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creator	Choi, Myung Gil Kim, Na Yeong Lee, Yu Jeong Ahn, Sangdoo Chang, Suk-Kyu
description	The first hydride-Meisenheimer adduct of 3-nitronaphthalimide was used for the colorimetric borohydride assay. To explain the regioselectivity of the adduct, the reaction enthalpies of the two most plausible Meisenheimer adducts were obtained via computational calculation. Using the adduct formation, the assay of borohydride reagents was successfully conducted. The first hydride-Meisenheimer adduct of electron-deficient 3-nitronaphthalimide was prepared, and the adduct formation was applied to the colorimetric borohydride assay.
doi_str_mv	10.1039/c9cc05597e
format	Article
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source	Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects	Adducts Borohydrides Colorimetry Enthalpy Hydrides Mathematical analysis NMR Nuclear magnetic resonance Reagents Regioselectivity
title	The first hydride-Meisenheimer adduct of electron-deficient 3-nitronaphthalimide: application to colorimetric borohydride determination
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