Construction and interconversion of anion-coordination-based ('aniono') grids and double helicates modulated by counter-cations
Supramolecular assembly of well-defined discrete architectures has been of great interest due to the tunable properties of these structures in functional materials and bio-mimicking. While metal-coordination-driven assembly has been extensively studied, anion-coordination-driven assembly (ACDA) is j...
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| Veröffentlicht in: | Chemical science (Cambridge) 2019-07, Vol.1 (25), p.6278-6284 |
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| creator | Fan, Xiaoxia Zhang, Dan Jiang, Shiyu Wang, Heng Lin, Lin-Ting Zheng, Bo Xu, Wen-Hua Zhao, Yanxia Hay, Benjamin P Chan, Yi-Tsu Yang, Xiao-Juan Li, Xiaopeng Wu, Biao |
| description | Supramolecular assembly of well-defined discrete architectures has been of great interest due to the tunable properties of these structures in functional materials and bio-mimicking. While metal-coordination-driven assembly has been extensively studied, anion-coordination-driven assembly (ACDA) is just emerging for constructing complex supramolecular structures. Herein two A
2
n
L
2
n
(A = anion,
L
= ligand;
n
= 1 or 2) 'aniono'-supramolecular assemblies,
i.e.
double helicates and the first anion grid, have been constructed based on the coordination between phosphate (PO
4
3−
) anion and a bis-tris(urea) ligand. Moreover, the aniono-grid and double helicate motifs can be readily interconverted under ambient conditions by simply changing the counter-cation. These results redefine the power and scope of ACDA, which may represent a new approach in the assembly of well-defined architectures in parallel with the metal coordination-driven assembly of metallo-supramolecules.
'Aniono' double helicates and grids were constructed using PO
4
3−
anions and a bis-tris(urea) ligand and interconverted by changing the counter-cation. |
| doi_str_mv | 10.1039/c9sc02012h |
| format | Article |
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2
n
L
2
n
(A = anion,
L
= ligand;
n
= 1 or 2) 'aniono'-supramolecular assemblies,
i.e.
double helicates and the first anion grid, have been constructed based on the coordination between phosphate (PO
4
3−
) anion and a bis-tris(urea) ligand. Moreover, the aniono-grid and double helicate motifs can be readily interconverted under ambient conditions by simply changing the counter-cation. These results redefine the power and scope of ACDA, which may represent a new approach in the assembly of well-defined architectures in parallel with the metal coordination-driven assembly of metallo-supramolecules.
'Aniono' double helicates and grids were constructed using PO
4
3−
anions and a bis-tris(urea) ligand and interconverted by changing the counter-cation.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/c9sc02012h</identifier><identifier>PMID: 31341580</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Anions ; Assembly ; Cations ; Chemistry ; Construction ; Coordination ; Crystallography ; Functional materials ; Ligands ; Metallography</subject><ispartof>Chemical science (Cambridge), 2019-07, Vol.1 (25), p.6278-6284</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><rights>This journal is © The Royal Society of Chemistry 2019 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c428t-5cbff56176033c5a16e0f426640589b7874ee89e0f9546d8da9c104a5a4a9a3b3</citedby><cites>FETCH-LOGICAL-c428t-5cbff56176033c5a16e0f426640589b7874ee89e0f9546d8da9c104a5a4a9a3b3</cites><orcidid>0000-0002-0869-4460 ; 0000-0001-9658-2188 ; 0000-0001-5096-8114 ; 0000-0002-0724-4150 ; 0000-0001-9172-9478 ; 0000-0001-9655-9551</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6598520/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6598520/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31341580$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fan, Xiaoxia</creatorcontrib><creatorcontrib>Zhang, Dan</creatorcontrib><creatorcontrib>Jiang, Shiyu</creatorcontrib><creatorcontrib>Wang, Heng</creatorcontrib><creatorcontrib>Lin, Lin-Ting</creatorcontrib><creatorcontrib>Zheng, Bo</creatorcontrib><creatorcontrib>Xu, Wen-Hua</creatorcontrib><creatorcontrib>Zhao, Yanxia</creatorcontrib><creatorcontrib>Hay, Benjamin P</creatorcontrib><creatorcontrib>Chan, Yi-Tsu</creatorcontrib><creatorcontrib>Yang, Xiao-Juan</creatorcontrib><creatorcontrib>Li, Xiaopeng</creatorcontrib><creatorcontrib>Wu, Biao</creatorcontrib><title>Construction and interconversion of anion-coordination-based ('aniono') grids and double helicates modulated by counter-cations</title><title>Chemical science (Cambridge)</title><addtitle>Chem Sci</addtitle><description>Supramolecular assembly of well-defined discrete architectures has been of great interest due to the tunable properties of these structures in functional materials and bio-mimicking. While metal-coordination-driven assembly has been extensively studied, anion-coordination-driven assembly (ACDA) is just emerging for constructing complex supramolecular structures. Herein two A
2
n
L
2
n
(A = anion,
L
= ligand;
n
= 1 or 2) 'aniono'-supramolecular assemblies,
i.e.
double helicates and the first anion grid, have been constructed based on the coordination between phosphate (PO
4
3−
) anion and a bis-tris(urea) ligand. Moreover, the aniono-grid and double helicate motifs can be readily interconverted under ambient conditions by simply changing the counter-cation. These results redefine the power and scope of ACDA, which may represent a new approach in the assembly of well-defined architectures in parallel with the metal coordination-driven assembly of metallo-supramolecules.
'Aniono' double helicates and grids were constructed using PO
4
3−
anions and a bis-tris(urea) ligand and interconverted by changing the counter-cation.</description><subject>Anions</subject><subject>Assembly</subject><subject>Cations</subject><subject>Chemistry</subject><subject>Construction</subject><subject>Coordination</subject><subject>Crystallography</subject><subject>Functional materials</subject><subject>Ligands</subject><subject>Metallography</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdkstLxDAQxoMoKurFu1LwsCpU897mIkjxBYIH9RzSJHUj3USTVvDkv252V9dHLhm--fHNTCYA7CJ4giARp1okDTFEeLICNjGkqOSMiNVljOEG2EnpGeZDCGJ4vA42CCIUsQpugo86-NTHQfcu-EJ5Uzjf26iDf7MxzbTQZjkHpQ4hGufVjCwblawpDkfzVBgdFU_RmTQ3MGFoOltMbOe06m0qpsEMXY5M0bwXOgyzAqWe-6RtsNaqLtmdr3sLPF5ePNTX5e3d1U19fltqiqu-ZLppW8bRmOchNFOIW9hSzDmFrBLNuBpTayuRRcEoN5VRQiNIFVNUCUUasgXOFr4vQzO1RlvfR9XJl-imKr7LoJz8m_FuIp_Cm-RMVPkRs8Hhl0EMr4NNvZy6pG3XKW_DkCTGnGJMESIZPfiHPoch-jxepigXTHDGMnW8oHQMKUXbLptBUM5WK2txX89Xe53h_d_tL9HvRWZgbwHEpJfZn79BPgGQFKp3</recordid><startdate>20190707</startdate><enddate>20190707</enddate><creator>Fan, Xiaoxia</creator><creator>Zhang, Dan</creator><creator>Jiang, Shiyu</creator><creator>Wang, Heng</creator><creator>Lin, Lin-Ting</creator><creator>Zheng, Bo</creator><creator>Xu, Wen-Hua</creator><creator>Zhao, Yanxia</creator><creator>Hay, Benjamin P</creator><creator>Chan, Yi-Tsu</creator><creator>Yang, Xiao-Juan</creator><creator>Li, Xiaopeng</creator><creator>Wu, Biao</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-0869-4460</orcidid><orcidid>https://orcid.org/0000-0001-9658-2188</orcidid><orcidid>https://orcid.org/0000-0001-5096-8114</orcidid><orcidid>https://orcid.org/0000-0002-0724-4150</orcidid><orcidid>https://orcid.org/0000-0001-9172-9478</orcidid><orcidid>https://orcid.org/0000-0001-9655-9551</orcidid></search><sort><creationdate>20190707</creationdate><title>Construction and interconversion of anion-coordination-based ('aniono') grids and double helicates modulated by counter-cations</title><author>Fan, Xiaoxia ; Zhang, Dan ; Jiang, Shiyu ; Wang, Heng ; Lin, Lin-Ting ; Zheng, Bo ; Xu, Wen-Hua ; Zhao, Yanxia ; Hay, Benjamin P ; Chan, Yi-Tsu ; Yang, Xiao-Juan ; Li, Xiaopeng ; Wu, Biao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c428t-5cbff56176033c5a16e0f426640589b7874ee89e0f9546d8da9c104a5a4a9a3b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Anions</topic><topic>Assembly</topic><topic>Cations</topic><topic>Chemistry</topic><topic>Construction</topic><topic>Coordination</topic><topic>Crystallography</topic><topic>Functional materials</topic><topic>Ligands</topic><topic>Metallography</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fan, Xiaoxia</creatorcontrib><creatorcontrib>Zhang, Dan</creatorcontrib><creatorcontrib>Jiang, Shiyu</creatorcontrib><creatorcontrib>Wang, Heng</creatorcontrib><creatorcontrib>Lin, Lin-Ting</creatorcontrib><creatorcontrib>Zheng, Bo</creatorcontrib><creatorcontrib>Xu, Wen-Hua</creatorcontrib><creatorcontrib>Zhao, Yanxia</creatorcontrib><creatorcontrib>Hay, Benjamin P</creatorcontrib><creatorcontrib>Chan, Yi-Tsu</creatorcontrib><creatorcontrib>Yang, Xiao-Juan</creatorcontrib><creatorcontrib>Li, Xiaopeng</creatorcontrib><creatorcontrib>Wu, Biao</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fan, Xiaoxia</au><au>Zhang, Dan</au><au>Jiang, Shiyu</au><au>Wang, Heng</au><au>Lin, Lin-Ting</au><au>Zheng, Bo</au><au>Xu, Wen-Hua</au><au>Zhao, Yanxia</au><au>Hay, Benjamin P</au><au>Chan, Yi-Tsu</au><au>Yang, Xiao-Juan</au><au>Li, Xiaopeng</au><au>Wu, Biao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Construction and interconversion of anion-coordination-based ('aniono') grids and double helicates modulated by counter-cations</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2019-07-07</date><risdate>2019</risdate><volume>1</volume><issue>25</issue><spage>6278</spage><epage>6284</epage><pages>6278-6284</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Supramolecular assembly of well-defined discrete architectures has been of great interest due to the tunable properties of these structures in functional materials and bio-mimicking. While metal-coordination-driven assembly has been extensively studied, anion-coordination-driven assembly (ACDA) is just emerging for constructing complex supramolecular structures. Herein two A
2
n
L
2
n
(A = anion,
L
= ligand;
n
= 1 or 2) 'aniono'-supramolecular assemblies,
i.e.
double helicates and the first anion grid, have been constructed based on the coordination between phosphate (PO
4
3−
) anion and a bis-tris(urea) ligand. Moreover, the aniono-grid and double helicate motifs can be readily interconverted under ambient conditions by simply changing the counter-cation. These results redefine the power and scope of ACDA, which may represent a new approach in the assembly of well-defined architectures in parallel with the metal coordination-driven assembly of metallo-supramolecules.
'Aniono' double helicates and grids were constructed using PO
4
3−
anions and a bis-tris(urea) ligand and interconverted by changing the counter-cation.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>31341580</pmid><doi>10.1039/c9sc02012h</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-0869-4460</orcidid><orcidid>https://orcid.org/0000-0001-9658-2188</orcidid><orcidid>https://orcid.org/0000-0001-5096-8114</orcidid><orcidid>https://orcid.org/0000-0002-0724-4150</orcidid><orcidid>https://orcid.org/0000-0001-9172-9478</orcidid><orcidid>https://orcid.org/0000-0001-9655-9551</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2041-6520 |
| ispartof | Chemical science (Cambridge), 2019-07, Vol.1 (25), p.6278-6284 |
| issn | 2041-6520 2041-6539 |
| language | eng |
| recordid | cdi_pubmed_primary_31341580 |
| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; PubMed Central Open Access |
| subjects | Anions Assembly Cations Chemistry Construction Coordination Crystallography Functional materials Ligands Metallography |
| title | Construction and interconversion of anion-coordination-based ('aniono') grids and double helicates modulated by counter-cations |
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