Highly phosphorescent organopalladium() complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions

Dinuclear pincer-type cyclometalated Pd( ii ) complexes with foldable diacetylide ligands show crystallographically determined intramolecular Pd Pd contacts of 3.203-3.380 Å. In deoxygenated fluid solutions, these Pd( ii ) complexes are highly phosphorescent in the red region with emission quantum y...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2019-07, Vol.48 (28), p.1417-1421
Hauptverfasser:	Lin, Jinqiang, Zou, Chao, Zhang, Xiaobao, Gao, Qin, Suo, Sa, Zhuo, Qihang, Chang, Xiaoyong, Xie, Mo, Lu, Wei
Format:	Artikel
Sprache:	eng
Schlagworte:	Charge transfer Coordination compounds Crystallography Deoxygenation Excitation Ligands Palladium Phosphorescence
Online-Zugang:	Volltext
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