Simple NMR predictors of catalytic hydrogenation activity for [Rh(cod)Cl(NHC)] complexes featuring fluorinated NHC ligands

A series of imidazolium salts precursors for N -heterocyclic carbenes (NHCs) featuring fluoroaryl substituents have been prepared along with their selenides and rhodium complexes. Tests of the catalytic activity of the [Rh(cod)Cl(NHC)] complexes in the transfer hydrogenation of acetophenone with iPr...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2019-06, Vol.48 (25), p.9317-9327
Hauptverfasser:	Jamil, Mohamad Shazwan Shah, Alkaabi, Sultan, Brisdon, Alan K
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetophenone Carbenes Catalysis Catalytic activity Coordination compounds Crystallography Fluorination Hydrogenation NMR Nuclear magnetic resonance Rhodium Selenides
Online-Zugang:	Volltext
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