Coordination-driven assembly of a supramolecular square and oxidation to a tetra-ligand radical species
The design and synthesis of a supramolecular square was achieved by coordination-driven assembly of redox-active nickel( ii ) salen linkers and (ethylenediamine)palladium( ii ) nodes. The tetrameric geometry of the supramolecular structure was confirmed via MS, NMR, and electrochemical experiments....
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2019-05, Vol.55 (43), p.682-685 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Herasymchuk, Khrystyna Miller, Jessica J MacNeil, Gregory A Sergeenko, Ania S McKearney, Declan Goeb, Sébastien Sallé, Marc Leznoff, Daniel B Storr, Tim |
| description | The design and synthesis of a supramolecular square was achieved by coordination-driven assembly of redox-active nickel(
ii
) salen linkers and (ethylenediamine)palladium(
ii
) nodes. The tetrameric geometry of the supramolecular structure was confirmed
via
MS, NMR, and electrochemical experiments. While oxidation of the monomeric metalloligand Schiff-base affords a Ni(
iii
) species, oxidation of the coordination-driven assembly results in ligand radical formation.
The design and synthesis of a supramolecular square was achieved by coordination-driven assembly of redox-active nickel(
ii
) salen linkers and (ethylenediamine)palladium(
ii
) nodes. |
| doi_str_mv | 10.1039/c9cc02320h |
| format | Article |
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ii
) salen linkers and (ethylenediamine)palladium(
ii
) nodes. The tetrameric geometry of the supramolecular structure was confirmed
via
MS, NMR, and electrochemical experiments. While oxidation of the monomeric metalloligand Schiff-base affords a Ni(
iii
) species, oxidation of the coordination-driven assembly results in ligand radical formation.
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ii
) salen linkers and (ethylenediamine)palladium(
ii
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ii
) salen linkers and (ethylenediamine)palladium(
ii
) nodes. The tetrameric geometry of the supramolecular structure was confirmed
via
MS, NMR, and electrochemical experiments. While oxidation of the monomeric metalloligand Schiff-base affords a Ni(
iii
) species, oxidation of the coordination-driven assembly results in ligand radical formation.
The design and synthesis of a supramolecular square was achieved by coordination-driven assembly of redox-active nickel(
ii
) salen linkers and (ethylenediamine)palladium(
ii
) nodes.</description><subject>Chemical Sciences</subject><subject>Coordination chemistry</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpFkc1r3DAQxUVoycc2l9xbdGwCTiWNvLaOwbTdwEIvKfRmZGm8UZGtjWSH5r-PNrvdzEWD3k8P9B4hV5zdcgbqm1HGMAGCPZ6Qcw5LWZSy_vNht5eqqECWZ-Qipb8sDy_rU3IGnC2XUMM52TQhROtGPbkwFja6ZxypTgmHzr_Q0FNN07yNeggezex1pOlp1hGpHi0N_5x9e0inkMEJp6gL7zY7LWrrjPY0bdE4TJ_Ix177hJeHc0F-__j-0KyK9a-f983dujAgYSqM6euqrxABhRRcYFVaFKzCUqjO1L3NP-g60ApUZQCtBS47ELBUnMneSliQ673vo_btNrpBx5c2aNeu7tbt7i4HpVjJ5DPP7Nc9u43hacY0tYNLBr3XI4Y5tUIAVzmxHPKC3OxRE0NKEfujN2ftroS2UU3zVsIqw18OvnM3oD2i_1PPwOc9EJM5qu8twivpg4wE</recordid><startdate>20190528</startdate><enddate>20190528</enddate><creator>Herasymchuk, Khrystyna</creator><creator>Miller, Jessica J</creator><creator>MacNeil, Gregory A</creator><creator>Sergeenko, Ania S</creator><creator>McKearney, Declan</creator><creator>Goeb, Sébastien</creator><creator>Sallé, Marc</creator><creator>Leznoff, Daniel B</creator><creator>Storr, Tim</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-4601-6334</orcidid><orcidid>https://orcid.org/0000-0002-3426-2848</orcidid><orcidid>https://orcid.org/0000-0003-2470-0768</orcidid><orcidid>https://orcid.org/0000-0002-3163-6218</orcidid></search><sort><creationdate>20190528</creationdate><title>Coordination-driven assembly of a supramolecular square and oxidation to a tetra-ligand radical species</title><author>Herasymchuk, Khrystyna ; Miller, Jessica J ; MacNeil, Gregory A ; Sergeenko, Ania S ; McKearney, Declan ; Goeb, Sébastien ; Sallé, Marc ; Leznoff, Daniel B ; Storr, Tim</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c343t-ccf87f7ee3e24212e75de207e529bc8fd001bb3a9397c3edd314b32369104fd43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Chemical Sciences</topic><topic>Coordination chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Herasymchuk, Khrystyna</creatorcontrib><creatorcontrib>Miller, Jessica J</creatorcontrib><creatorcontrib>MacNeil, Gregory A</creatorcontrib><creatorcontrib>Sergeenko, Ania S</creatorcontrib><creatorcontrib>McKearney, Declan</creatorcontrib><creatorcontrib>Goeb, Sébastien</creatorcontrib><creatorcontrib>Sallé, Marc</creatorcontrib><creatorcontrib>Leznoff, Daniel B</creatorcontrib><creatorcontrib>Storr, Tim</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Herasymchuk, Khrystyna</au><au>Miller, Jessica J</au><au>MacNeil, Gregory A</au><au>Sergeenko, Ania S</au><au>McKearney, Declan</au><au>Goeb, Sébastien</au><au>Sallé, Marc</au><au>Leznoff, Daniel B</au><au>Storr, Tim</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coordination-driven assembly of a supramolecular square and oxidation to a tetra-ligand radical species</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2019-05-28</date><risdate>2019</risdate><volume>55</volume><issue>43</issue><spage>682</spage><epage>685</epage><pages>682-685</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The design and synthesis of a supramolecular square was achieved by coordination-driven assembly of redox-active nickel(
ii
) salen linkers and (ethylenediamine)palladium(
ii
) nodes. The tetrameric geometry of the supramolecular structure was confirmed
via
MS, NMR, and electrochemical experiments. While oxidation of the monomeric metalloligand Schiff-base affords a Ni(
iii
) species, oxidation of the coordination-driven assembly results in ligand radical formation.
The design and synthesis of a supramolecular square was achieved by coordination-driven assembly of redox-active nickel(
ii
) salen linkers and (ethylenediamine)palladium(
ii
) nodes.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>31066383</pmid><doi>10.1039/c9cc02320h</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-4601-6334</orcidid><orcidid>https://orcid.org/0000-0002-3426-2848</orcidid><orcidid>https://orcid.org/0000-0003-2470-0768</orcidid><orcidid>https://orcid.org/0000-0002-3163-6218</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2019-05, Vol.55 (43), p.682-685 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_pubmed_primary_31066383 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical Sciences Coordination chemistry |
| title | Coordination-driven assembly of a supramolecular square and oxidation to a tetra-ligand radical species |
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