Oxidation of uranium() thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains
Oxidation of Cs 4 [U(NCS) 8 ] in MeCN or DMF affords structurally characterised examples of the mixed-valent U IV/VI compound Cs 14 [{U(NCS) 8 } 3 {UO 2 (NCS) 4 (H 2 O)}]·4.5H 2 O, or the [U IV -U V -U IV ][U VI ] species [U(DMF) 8 (μ-O)U(NCS) 5 (μ-O)U(DMF) 7 (NCS)][UO 2 (NCS) 5 ]. Vibrational and m...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019-05, Vol.48 (2), p.674-678 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 48 |
| creator | Nuzzo, Stefano van Leusen, Jan Twamley, Brendan Platts, James A Kögerler, Paul Baker, Robert J |
| description | Oxidation of Cs
4
[U(NCS)
8
] in MeCN or DMF affords structurally characterised examples of the mixed-valent U
IV/VI
compound Cs
14
[{U(NCS)
8
}
3
{UO
2
(NCS)
4
(H
2
O)}]·4.5H
2
O, or the [U
IV
-U
V
-U
IV
][U
VI
] species [U(DMF)
8
(μ-O)U(NCS)
5
(μ-O)U(DMF)
7
(NCS)][UO
2
(NCS)
5
]. Vibrational and magnetism data support their oxidation state formulism, which is further corroborated by computational methodology.
Oxidation of Cs
4
[U(NCS)
8
] in different solvents results in two mixed-valent uranium compounds. Spectroscopic, magnetic and computational data support a unique [U
IV
U
V
U
IV
][U
VI
] oxidation state assignment in [U(DMF)
8
(μ-O)U(NCS)
5
(μ-O)U(DMF)
7
(NCS)][UO
2
(NCS)
5
]. |
| doi_str_mv | 10.1039/c9dt01005j |
| format | Article |
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4
[U(NCS)
8
] in MeCN or DMF affords structurally characterised examples of the mixed-valent U
IV/VI
compound Cs
14
[{U(NCS)
8
}
3
{UO
2
(NCS)
4
(H
2
O)}]·4.5H
2
O, or the [U
IV
-U
V
-U
IV
][U
VI
] species [U(DMF)
8
(μ-O)U(NCS)
5
(μ-O)U(DMF)
7
(NCS)][UO
2
(NCS)
5
]. Vibrational and magnetism data support their oxidation state formulism, which is further corroborated by computational methodology.
Oxidation of Cs
4
[U(NCS)
8
] in different solvents results in two mixed-valent uranium compounds. Spectroscopic, magnetic and computational data support a unique [U
IV
U
V
U
IV
][U
VI
] oxidation state assignment in [U(DMF)
8
(μ-O)U(NCS)
5
(μ-O)U(DMF)
7
(NCS)][UO
2
(NCS)
5
].</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c9dt01005j</identifier><identifier>PMID: 31041967</identifier><language>eng</language><publisher>England</publisher><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2019-05, Vol.48 (2), p.674-678</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c411t-4745e18c204a1aa199df5f8399dd5823b62769e81adc298d3b58f10ad83af70b3</citedby><cites>FETCH-LOGICAL-c411t-4745e18c204a1aa199df5f8399dd5823b62769e81adc298d3b58f10ad83af70b3</cites><orcidid>0000-0003-3688-631X ; 0000-0001-7831-3953 ; 0000-0003-1416-8659</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31041967$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Nuzzo, Stefano</creatorcontrib><creatorcontrib>van Leusen, Jan</creatorcontrib><creatorcontrib>Twamley, Brendan</creatorcontrib><creatorcontrib>Platts, James A</creatorcontrib><creatorcontrib>Kögerler, Paul</creatorcontrib><creatorcontrib>Baker, Robert J</creatorcontrib><title>Oxidation of uranium() thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Oxidation of Cs
4
[U(NCS)
8
] in MeCN or DMF affords structurally characterised examples of the mixed-valent U
IV/VI
compound Cs
14
[{U(NCS)
8
}
3
{UO
2
(NCS)
4
(H
2
O)}]·4.5H
2
O, or the [U
IV
-U
V
-U
IV
][U
VI
] species [U(DMF)
8
(μ-O)U(NCS)
5
(μ-O)U(DMF)
7
(NCS)][UO
2
(NCS)
5
]. Vibrational and magnetism data support their oxidation state formulism, which is further corroborated by computational methodology.
Oxidation of Cs
4
[U(NCS)
8
] in different solvents results in two mixed-valent uranium compounds. Spectroscopic, magnetic and computational data support a unique [U
IV
U
V
U
IV
][U
VI
] oxidation state assignment in [U(DMF)
8
(μ-O)U(NCS)
5
(μ-O)U(DMF)
7
(NCS)][UO
2
(NCS)
5
].</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpFkUtPwzAQhC0EoqVw4Q7KsSAF_Epic0PlrUq9lHPk2I7qKnGK7aD235M2bTnNrPbbOcwCcI3gA4KEP0quAkQQJssTMEQ0y2KOCT09epwOwIX3Swgxhgk-BwOCIEU8zYYgzNZGiWAaGzVl1DphTVuP76KwMI3cCCuCjmRTryq91v4pkjs07iUyNmgn5Nb7bohqs9Yq_hWVtuGQ1V03ThnbX8iFMNZfgrNSVF5f7XUEvt9e55OPeDp7_5w8T2NJEQoxzWiiEZMYUoGEQJyrMikZ6VQlDJMixVnKNUNCScyZIkXCSgSFYkSUGSzICIz73JVrflrtQ14bL3VVCaub1ucYI0ZgSnnSofc9Kl3jvdNlvnKmFm6TI5hvW84n_GW-a_mrg2_3uW1Ra3VED7V2wE0POC-P2_83kT-L_oOd</recordid><startdate>20190521</startdate><enddate>20190521</enddate><creator>Nuzzo, Stefano</creator><creator>van Leusen, Jan</creator><creator>Twamley, Brendan</creator><creator>Platts, James A</creator><creator>Kögerler, Paul</creator><creator>Baker, Robert J</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3688-631X</orcidid><orcidid>https://orcid.org/0000-0001-7831-3953</orcidid><orcidid>https://orcid.org/0000-0003-1416-8659</orcidid></search><sort><creationdate>20190521</creationdate><title>Oxidation of uranium() thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains</title><author>Nuzzo, Stefano ; van Leusen, Jan ; Twamley, Brendan ; Platts, James A ; Kögerler, Paul ; Baker, Robert J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c411t-4745e18c204a1aa199df5f8399dd5823b62769e81adc298d3b58f10ad83af70b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nuzzo, Stefano</creatorcontrib><creatorcontrib>van Leusen, Jan</creatorcontrib><creatorcontrib>Twamley, Brendan</creatorcontrib><creatorcontrib>Platts, James A</creatorcontrib><creatorcontrib>Kögerler, Paul</creatorcontrib><creatorcontrib>Baker, Robert J</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nuzzo, Stefano</au><au>van Leusen, Jan</au><au>Twamley, Brendan</au><au>Platts, James A</au><au>Kögerler, Paul</au><au>Baker, Robert J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxidation of uranium() thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2019-05-21</date><risdate>2019</risdate><volume>48</volume><issue>2</issue><spage>674</spage><epage>678</epage><pages>674-678</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Oxidation of Cs
4
[U(NCS)
8
] in MeCN or DMF affords structurally characterised examples of the mixed-valent U
IV/VI
compound Cs
14
[{U(NCS)
8
}
3
{UO
2
(NCS)
4
(H
2
O)}]·4.5H
2
O, or the [U
IV
-U
V
-U
IV
][U
VI
] species [U(DMF)
8
(μ-O)U(NCS)
5
(μ-O)U(DMF)
7
(NCS)][UO
2
(NCS)
5
]. Vibrational and magnetism data support their oxidation state formulism, which is further corroborated by computational methodology.
Oxidation of Cs
4
[U(NCS)
8
] in different solvents results in two mixed-valent uranium compounds. Spectroscopic, magnetic and computational data support a unique [U
IV
U
V
U
IV
][U
VI
] oxidation state assignment in [U(DMF)
8
(μ-O)U(NCS)
5
(μ-O)U(DMF)
7
(NCS)][UO
2
(NCS)
5
].</abstract><cop>England</cop><pmid>31041967</pmid><doi>10.1039/c9dt01005j</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-3688-631X</orcidid><orcidid>https://orcid.org/0000-0001-7831-3953</orcidid><orcidid>https://orcid.org/0000-0003-1416-8659</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2019-05, Vol.48 (2), p.674-678 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_pubmed_primary_31041967 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Oxidation of uranium() thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains |
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