The efficiency of UV/S 2 O 8 2- photo-oxidation process in the presence of Al 2 O 3 for the removal of dexamethasone from aqueous solution: kinetic studies
This study aimed to investigate the efficiency of the UV/S O photocatalytic process in the presence of Al O nanoparticles for the removal of dexamethasone from aqueous solution. In this experimental study, the variables pH, persulfate concentration, initial concentration of dexamethasone, the cataly...
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| Veröffentlicht in: | Water science and technology 2019-03, Vol.79 (5), p.938 |
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| creator | Shookohi, Reza Faraji, Hossein Arabkohsar, Abolfazl Salari, Mehdi Mahmoudi, Mohammad Molla |
| description | This study aimed to investigate the efficiency of the UV/S
O
photocatalytic process in the presence of Al
O
nanoparticles for the removal of dexamethasone from aqueous solution. In this experimental study, the variables pH, persulfate concentration, initial concentration of dexamethasone, the catalyst dose were studied in order to investigate the process efficiency. Furthermore, the efficiency of UV/S
O
in the presence and absence of catalyst was investigated. The Al
O
nanoparticle catalyst was characterized using X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analyses and scanning electron microscopy (SEM) image. The results showed that a decrease in pH and the initial concentration of dexamethasone increased the process efficiency. Given the increased concentrations of the persulfate and Al
O
, the removal efficiency was partially increased. In UV/S
O
/Al
O
under optimum conditions (pH = 3, t = 30 minutes, dexamethasone concentration = 20 mg/L, 0.5 mM of persulfate, and UV radiation = 55 watts), 94% of the dexamethasone was removed. The kinetic response showed that the reaction data corresponded to the pseudo-first-order kinetic model. The results showed that the UV/S
O
photochemical process can efficiently remove dexamethasone from aqueous solution in the presence of Al
O
catalyst and the mineralization efficiency reached about 98%. Therefore, this process is recommended due to its high efficiency and availability for the removal of pharmaceutical compounds. |
| doi_str_mv | 10.2166/wst.2019.109 |
| format | Article |
| fullrecord | <record><control><sourceid>pubmed</sourceid><recordid>TN_cdi_pubmed_primary_31025973</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>31025973</sourcerecordid><originalsourceid>FETCH-pubmed_primary_310259733</originalsourceid><addsrcrecordid>eNqFj7tOw0AQRbcAkfDoqNH8gJ19QIzpEAKloyBJGy32rLxg75idNSTfws8SR1BT3eLcc6UrxKWSuVbz-eyLU66lKnMlyyMxlbowmdLaTMQp85uUsjDX8kRMjJL6pizMVHwvGwR0zlceQ7UDcrBaz15AwzPcgs6gbyhRRltf2-QpQB-pQmbwAdJe7SPyXsRRvG8PmgFH8QAjdvRp25HVuLUdpsYyBQQXqQP7MSANDEztME7fwbsPmHwFnIbaI5-LY2dbxovfPBNXT4_Lh0XWD68d1ps--s7G3ebvjfm38ANpQ1oB</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>The efficiency of UV/S 2 O 8 2- photo-oxidation process in the presence of Al 2 O 3 for the removal of dexamethasone from aqueous solution: kinetic studies</title><source>MEDLINE</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><creator>Shookohi, Reza ; Faraji, Hossein ; Arabkohsar, Abolfazl ; Salari, Mehdi ; Mahmoudi, Mohammad Molla</creator><creatorcontrib>Shookohi, Reza ; Faraji, Hossein ; Arabkohsar, Abolfazl ; Salari, Mehdi ; Mahmoudi, Mohammad Molla</creatorcontrib><description>This study aimed to investigate the efficiency of the UV/S
O
photocatalytic process in the presence of Al
O
nanoparticles for the removal of dexamethasone from aqueous solution. In this experimental study, the variables pH, persulfate concentration, initial concentration of dexamethasone, the catalyst dose were studied in order to investigate the process efficiency. Furthermore, the efficiency of UV/S
O
in the presence and absence of catalyst was investigated. The Al
O
nanoparticle catalyst was characterized using X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analyses and scanning electron microscopy (SEM) image. The results showed that a decrease in pH and the initial concentration of dexamethasone increased the process efficiency. Given the increased concentrations of the persulfate and Al
O
, the removal efficiency was partially increased. In UV/S
O
/Al
O
under optimum conditions (pH = 3, t = 30 minutes, dexamethasone concentration = 20 mg/L, 0.5 mM of persulfate, and UV radiation = 55 watts), 94% of the dexamethasone was removed. The kinetic response showed that the reaction data corresponded to the pseudo-first-order kinetic model. The results showed that the UV/S
O
photochemical process can efficiently remove dexamethasone from aqueous solution in the presence of Al
O
catalyst and the mineralization efficiency reached about 98%. Therefore, this process is recommended due to its high efficiency and availability for the removal of pharmaceutical compounds.</description><identifier>ISSN: 0273-1223</identifier><identifier>DOI: 10.2166/wst.2019.109</identifier><identifier>PMID: 31025973</identifier><language>eng</language><publisher>England</publisher><subject>Catalysis ; Dexamethasone - analysis ; Dexamethasone - chemistry ; Kinetics ; Oxidation-Reduction ; Ultraviolet Rays ; Water Pollutants, Chemical - analysis ; Water Pollutants, Chemical - chemistry ; Water Purification - methods</subject><ispartof>Water science and technology, 2019-03, Vol.79 (5), p.938</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31025973$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shookohi, Reza</creatorcontrib><creatorcontrib>Faraji, Hossein</creatorcontrib><creatorcontrib>Arabkohsar, Abolfazl</creatorcontrib><creatorcontrib>Salari, Mehdi</creatorcontrib><creatorcontrib>Mahmoudi, Mohammad Molla</creatorcontrib><title>The efficiency of UV/S 2 O 8 2- photo-oxidation process in the presence of Al 2 O 3 for the removal of dexamethasone from aqueous solution: kinetic studies</title><title>Water science and technology</title><addtitle>Water Sci Technol</addtitle><description>This study aimed to investigate the efficiency of the UV/S
O
photocatalytic process in the presence of Al
O
nanoparticles for the removal of dexamethasone from aqueous solution. In this experimental study, the variables pH, persulfate concentration, initial concentration of dexamethasone, the catalyst dose were studied in order to investigate the process efficiency. Furthermore, the efficiency of UV/S
O
in the presence and absence of catalyst was investigated. The Al
O
nanoparticle catalyst was characterized using X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analyses and scanning electron microscopy (SEM) image. The results showed that a decrease in pH and the initial concentration of dexamethasone increased the process efficiency. Given the increased concentrations of the persulfate and Al
O
, the removal efficiency was partially increased. In UV/S
O
/Al
O
under optimum conditions (pH = 3, t = 30 minutes, dexamethasone concentration = 20 mg/L, 0.5 mM of persulfate, and UV radiation = 55 watts), 94% of the dexamethasone was removed. The kinetic response showed that the reaction data corresponded to the pseudo-first-order kinetic model. The results showed that the UV/S
O
photochemical process can efficiently remove dexamethasone from aqueous solution in the presence of Al
O
catalyst and the mineralization efficiency reached about 98%. Therefore, this process is recommended due to its high efficiency and availability for the removal of pharmaceutical compounds.</description><subject>Catalysis</subject><subject>Dexamethasone - analysis</subject><subject>Dexamethasone - chemistry</subject><subject>Kinetics</subject><subject>Oxidation-Reduction</subject><subject>Ultraviolet Rays</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water Purification - methods</subject><issn>0273-1223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFj7tOw0AQRbcAkfDoqNH8gJ19QIzpEAKloyBJGy32rLxg75idNSTfws8SR1BT3eLcc6UrxKWSuVbz-eyLU66lKnMlyyMxlbowmdLaTMQp85uUsjDX8kRMjJL6pizMVHwvGwR0zlceQ7UDcrBaz15AwzPcgs6gbyhRRltf2-QpQB-pQmbwAdJe7SPyXsRRvG8PmgFH8QAjdvRp25HVuLUdpsYyBQQXqQP7MSANDEztME7fwbsPmHwFnIbaI5-LY2dbxovfPBNXT4_Lh0XWD68d1ps--s7G3ebvjfm38ANpQ1oB</recordid><startdate>201903</startdate><enddate>201903</enddate><creator>Shookohi, Reza</creator><creator>Faraji, Hossein</creator><creator>Arabkohsar, Abolfazl</creator><creator>Salari, Mehdi</creator><creator>Mahmoudi, Mohammad Molla</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope></search><sort><creationdate>201903</creationdate><title>The efficiency of UV/S 2 O 8 2- photo-oxidation process in the presence of Al 2 O 3 for the removal of dexamethasone from aqueous solution: kinetic studies</title><author>Shookohi, Reza ; Faraji, Hossein ; Arabkohsar, Abolfazl ; Salari, Mehdi ; Mahmoudi, Mohammad Molla</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_310259733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Catalysis</topic><topic>Dexamethasone - analysis</topic><topic>Dexamethasone - chemistry</topic><topic>Kinetics</topic><topic>Oxidation-Reduction</topic><topic>Ultraviolet Rays</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water Pollutants, Chemical - chemistry</topic><topic>Water Purification - methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shookohi, Reza</creatorcontrib><creatorcontrib>Faraji, Hossein</creatorcontrib><creatorcontrib>Arabkohsar, Abolfazl</creatorcontrib><creatorcontrib>Salari, Mehdi</creatorcontrib><creatorcontrib>Mahmoudi, Mohammad Molla</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><jtitle>Water science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shookohi, Reza</au><au>Faraji, Hossein</au><au>Arabkohsar, Abolfazl</au><au>Salari, Mehdi</au><au>Mahmoudi, Mohammad Molla</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The efficiency of UV/S 2 O 8 2- photo-oxidation process in the presence of Al 2 O 3 for the removal of dexamethasone from aqueous solution: kinetic studies</atitle><jtitle>Water science and technology</jtitle><addtitle>Water Sci Technol</addtitle><date>2019-03</date><risdate>2019</risdate><volume>79</volume><issue>5</issue><spage>938</spage><pages>938-</pages><issn>0273-1223</issn><abstract>This study aimed to investigate the efficiency of the UV/S
O
photocatalytic process in the presence of Al
O
nanoparticles for the removal of dexamethasone from aqueous solution. In this experimental study, the variables pH, persulfate concentration, initial concentration of dexamethasone, the catalyst dose were studied in order to investigate the process efficiency. Furthermore, the efficiency of UV/S
O
in the presence and absence of catalyst was investigated. The Al
O
nanoparticle catalyst was characterized using X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analyses and scanning electron microscopy (SEM) image. The results showed that a decrease in pH and the initial concentration of dexamethasone increased the process efficiency. Given the increased concentrations of the persulfate and Al
O
, the removal efficiency was partially increased. In UV/S
O
/Al
O
under optimum conditions (pH = 3, t = 30 minutes, dexamethasone concentration = 20 mg/L, 0.5 mM of persulfate, and UV radiation = 55 watts), 94% of the dexamethasone was removed. The kinetic response showed that the reaction data corresponded to the pseudo-first-order kinetic model. The results showed that the UV/S
O
photochemical process can efficiently remove dexamethasone from aqueous solution in the presence of Al
O
catalyst and the mineralization efficiency reached about 98%. Therefore, this process is recommended due to its high efficiency and availability for the removal of pharmaceutical compounds.</abstract><cop>England</cop><pmid>31025973</pmid><doi>10.2166/wst.2019.109</doi></addata></record> |
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| ispartof | Water science and technology, 2019-03, Vol.79 (5), p.938 |
| issn | 0273-1223 |
| language | eng |
| recordid | cdi_pubmed_primary_31025973 |
| source | MEDLINE; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
| subjects | Catalysis Dexamethasone - analysis Dexamethasone - chemistry Kinetics Oxidation-Reduction Ultraviolet Rays Water Pollutants, Chemical - analysis Water Pollutants, Chemical - chemistry Water Purification - methods |
| title | The efficiency of UV/S 2 O 8 2- photo-oxidation process in the presence of Al 2 O 3 for the removal of dexamethasone from aqueous solution: kinetic studies |
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