Pore-tuning to boost the electrocatalytic activity of polymeric micelle-templated mesoporous Pd nanoparticles

Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts. Herein, by using polymeric micelle-assembled structures as templates, mesoporous Pd nanoparticles with tunable po...

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Veröffentlicht in:Chemical science (Cambridge) 2019-04, Vol.1 (14), p.454-461
Hauptverfasser: Li, Cuiling, Iqbal, Muhammad, Jiang, Bo, Wang, Zhongli, Kim, Jeonghun, Nanjundan, Ashok Kumar, Whitten, Andrew E, Wood, Kathleen, Yamauchi, Yusuke
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container_end_page 461
container_issue 14
container_start_page 454
container_title Chemical science (Cambridge)
container_volume 1
creator Li, Cuiling
Iqbal, Muhammad
Jiang, Bo
Wang, Zhongli
Kim, Jeonghun
Nanjundan, Ashok Kumar
Whitten, Andrew E
Wood, Kathleen
Yamauchi, Yusuke
description Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts. Herein, by using polymeric micelle-assembled structures as templates, mesoporous Pd nanoparticles with tunable porous constructions are synthesized by simply tuning the solvent compositions. The effect of porous Pd nanoparticles on the electrocatalytic performance is thoroughly studied. Their superior electrocatalytic activity can be attributed to the mass transport efficiency and open porous structures. Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts.
doi_str_mv 10.1039/c8sc03911a
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source DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central
subjects Composition effects
Electrocatalysts
Micelles
Nanoparticles
Noble metals
Oxidation
Palladium
Tuning
title Pore-tuning to boost the electrocatalytic activity of polymeric micelle-templated mesoporous Pd nanoparticles
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