Pore-tuning to boost the electrocatalytic activity of polymeric micelle-templated mesoporous Pd nanoparticles
Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts. Herein, by using polymeric micelle-assembled structures as templates, mesoporous Pd nanoparticles with tunable po...
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Veröffentlicht in: | Chemical science (Cambridge) 2019-04, Vol.1 (14), p.454-461 |
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creator | Li, Cuiling Iqbal, Muhammad Jiang, Bo Wang, Zhongli Kim, Jeonghun Nanjundan, Ashok Kumar Whitten, Andrew E Wood, Kathleen Yamauchi, Yusuke |
description | Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts. Herein, by using polymeric micelle-assembled structures as templates, mesoporous Pd nanoparticles with tunable porous constructions are synthesized by simply tuning the solvent compositions. The effect of porous Pd nanoparticles on the electrocatalytic performance is thoroughly studied. Their superior electrocatalytic activity can be attributed to the mass transport efficiency and open porous structures.
Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts. |
doi_str_mv | 10.1039/c8sc03911a |
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Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts.</description><subject>Composition effects</subject><subject>Electrocatalysts</subject><subject>Micelles</subject><subject>Nanoparticles</subject><subject>Noble metals</subject><subject>Oxidation</subject><subject>Palladium</subject><subject>Tuning</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdkc1LxDAQxYMo7rLuxbsS8CJCNdO03ea4FL9AcEE9lzSdape2qUkq9L83664rOJcZJj8eb_IIOQV2DYyLG5Va5TuAPCDTkEUQJDEXh_s5ZBMyt3bNfHEOcbg4JhMODGIRJVPSrrTBwA1d3b1Tp2mhtXXUfSDFBpUzWkknm9HVikrl6q_ajVRXtNfN2KLx27ZW2DReAtu-kQ5L2qLVvTZ6sHRV0k52upfGCzRoT8hRJRuL812fkbe729fsIXh6vn_Mlk-BirhwgULBBEPFiiSCBVNlAWXpb5TgdwiYAmIZx9UCilTKuIiqhCdsUYgwTVRUcT4jl1vd3ujPAa3L29pufMoOva88DMHLxTEDj178Q9d6MJ135ynGmRCe9dTVllJGW2uwyntTt9KMObB8k0OepS_ZTw5LD5_vJIeixXKP_v66B862gLFq__oXJP8GuDKOKA</recordid><startdate>20190414</startdate><enddate>20190414</enddate><creator>Li, Cuiling</creator><creator>Iqbal, Muhammad</creator><creator>Jiang, Bo</creator><creator>Wang, Zhongli</creator><creator>Kim, Jeonghun</creator><creator>Nanjundan, Ashok Kumar</creator><creator>Whitten, Andrew E</creator><creator>Wood, Kathleen</creator><creator>Yamauchi, Yusuke</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6502-0844</orcidid><orcidid>https://orcid.org/0000-0001-7854-927X</orcidid><orcidid>https://orcid.org/0000-0003-2283-579X</orcidid><orcidid>https://orcid.org/0000-0001-6325-0507</orcidid></search><sort><creationdate>20190414</creationdate><title>Pore-tuning to boost the electrocatalytic activity of polymeric micelle-templated mesoporous Pd nanoparticles</title><author>Li, Cuiling ; Iqbal, Muhammad ; Jiang, Bo ; Wang, Zhongli ; Kim, Jeonghun ; Nanjundan, Ashok Kumar ; Whitten, Andrew E ; Wood, Kathleen ; Yamauchi, Yusuke</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c439t-ce9090ec0b64170cdb1dd391a1ec0e1e81eed55f71b8aa5b4f63607b9286c4f33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Composition effects</topic><topic>Electrocatalysts</topic><topic>Micelles</topic><topic>Nanoparticles</topic><topic>Noble metals</topic><topic>Oxidation</topic><topic>Palladium</topic><topic>Tuning</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Cuiling</creatorcontrib><creatorcontrib>Iqbal, Muhammad</creatorcontrib><creatorcontrib>Jiang, Bo</creatorcontrib><creatorcontrib>Wang, Zhongli</creatorcontrib><creatorcontrib>Kim, Jeonghun</creatorcontrib><creatorcontrib>Nanjundan, Ashok Kumar</creatorcontrib><creatorcontrib>Whitten, Andrew E</creatorcontrib><creatorcontrib>Wood, Kathleen</creatorcontrib><creatorcontrib>Yamauchi, Yusuke</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Cuiling</au><au>Iqbal, Muhammad</au><au>Jiang, Bo</au><au>Wang, Zhongli</au><au>Kim, Jeonghun</au><au>Nanjundan, Ashok Kumar</au><au>Whitten, Andrew E</au><au>Wood, Kathleen</au><au>Yamauchi, Yusuke</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pore-tuning to boost the electrocatalytic activity of polymeric micelle-templated mesoporous Pd nanoparticles</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2019-04-14</date><risdate>2019</risdate><volume>1</volume><issue>14</issue><spage>454</spage><epage>461</epage><pages>454-461</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts. Herein, by using polymeric micelle-assembled structures as templates, mesoporous Pd nanoparticles with tunable porous constructions are synthesized by simply tuning the solvent compositions. The effect of porous Pd nanoparticles on the electrocatalytic performance is thoroughly studied. Their superior electrocatalytic activity can be attributed to the mass transport efficiency and open porous structures.
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source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central |
subjects | Composition effects Electrocatalysts Micelles Nanoparticles Noble metals Oxidation Palladium Tuning |
title | Pore-tuning to boost the electrocatalytic activity of polymeric micelle-templated mesoporous Pd nanoparticles |
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