Tough and electro-responsive hydrogel actuators with bidirectional bending behavior

Electro-responsive hydrogel actuators have gained much attention because of their fast response, low power consumption and easy modulation. However, such hydrogel actuators suffer from poor mechanical properties and restricted bending direction, which limit their practical applications. Herein, we report a nanocomposite hydrogel actuator with a combination of high mechanical tensile strength (2 MPa) and automatic bidirectional bending behavior in response to electric signals. The resulting hydrogel, crosslinked by aluminum hydroxide nanoparticles, shows rapid bending behavior and could be cyclically actuated up to ten times in an electric field. Furthermore, the hydrogel demonstrates bidirectional bending actuation, which was ascribed to the difference in diffusion coefficients and concentrations of cations and anions within the gel network. Moreover, the direction and magnitude of the bending behavior could be tuned by composition variation. The hydrogel actuators developed in this study may have great potential in soft robotics, artificial muscles and tissue engineering. A tough and electro-responsive hydrogel actuator exhibits fast, cyclic and bidirectional bending behavior.