Terminal Ligand (L) Effects on Zero-Magnetic-Field Splitting in the Excited Triplet States of [{Mo 6 Br 8 }L 6 ] 2- (L = Aromatic Carboxylates)
We report the emission properties of the octahedral hexamolybdenum(II) bromide-core ({Mo Br } ) clusters having a series of terminal aromatic carboxylate ligands (RCOO), [{Mo Br }(RCOO) ] , in solution and crystalline phases. The acid dissociation constant of RCOOH (p K (L)) was shown to govern the...
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| Veröffentlicht in: | Inorganic chemistry 2018-12 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
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