Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions

Polydioxirane (PDOX) was prepared by the treatment of polysalicylaldehyde with Oxone and was found as a selective, highly efficient and heterogeneous reagent for epoxidation of alkenes which can be successfully isolated. This work also introduced a simpler, safer and milder way for epoxidation of al...

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Veröffentlicht in:	Royal Society open science 2018-05, Vol.5 (5), p.171541-171541
Hauptverfasser:	Kazemnejadi, M., Shakeri, A., Nikookar, M., Shademani, R., Mohammadi, M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Epoxidation Mild Conditions Polydioxirane Polysalicylaldehyde Recoverability Terminal Alkene
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creator	Kazemnejadi, M. Shakeri, A. Nikookar, M. Shademani, R. Mohammadi, M.
description	Polydioxirane (PDOX) was prepared by the treatment of polysalicylaldehyde with Oxone and was found as a selective, highly efficient and heterogeneous reagent for epoxidation of alkenes which can be successfully isolated. This work also introduced a simpler, safer and milder way for epoxidation of alkenes with dioxirane groups than before. PDOX can be simply recovered from the reaction mixture by plain filtration and reused for eight runs without significant reactivity loss.
doi_str_mv	10.1098/rsos.171541
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source	DOAJ Directory of Open Access Journals; Royal Society Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central
subjects	Chemistry Epoxidation Mild Conditions Polydioxirane Polysalicylaldehyde Recoverability Terminal Alkene
title	Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions
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