Substitution-Induced Structure Evolution and Zn 2+ /Ga 3+ Ordering in "114" Oxides MAZn 2 Ga 2 O 7 ( M = Ca 2+ , Sr 2+ ; A = Sr 2+ , Ba 2+ )
The "114" oxides LnBa(Co/Fe) O represent a new family of materials that exhibits intriguing physical properties, including geometrically frustrated magnetism, oxygen storage, and magnetoelectric couplings. Various chemical substitutions have been conducted to modify their crystal and magne...
Gespeichert in:
Veröffentlicht in: | Inorganic chemistry 2018-06 |
---|---|
Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | |
container_start_page | |
container_title | Inorganic chemistry |
container_volume | |
creator | Jiang, Pengfei Huang, Qingzhen Avdeev, Maxim Tao, Fengqiong Zhou, Lijia Gao, Wenliang Cong, Rihong Yang, Tao |
description | The "114" oxides LnBa(Co/Fe)
O
represent a new family of materials that exhibits intriguing physical properties, including geometrically frustrated magnetism, oxygen storage, and magnetoelectric couplings. Various chemical substitutions have been conducted to modify their crystal and magnetic structures as well as physical properties. However, the principles beneath the substitution-induced structural evolution and charge/cationic ordering have not yet been understood. Thus, in this contribution, two complete solid solutions of MAZn
Ga
O
( M = Ca
, Sr
; A = Sr
, Ba
) were designed, synthesized, and characterized by Rietveld refinements based on high-resolution X-ray diffraction (XRD) and neutron diffraction (ND) data. The structure symmetry of MAZn
Ga
O
is determined by the cationic size mismatch between M and A cations that can be defined by the tolerance factor t, i.e., symmetry transitions from P6
mc ( t > 0.87) to P31 c (0.87 > t > 0.75) and to Pna2
( t < 0.75) were observed for MAZn
Ga
O
, associated with the rotation of T1O
tetrahedra in the triangular layers. The Zn
/Ga
ordering at T sites is also a consequence of the increase or decrease of the average sizes of M and A cations. A small concentration of interstitial oxygen ions can be obtained in Sr
Zn
Ga
O
( x = 0.1, 0.2); however, no oxygen ionic conduction was observed at high temperatures, indicating the migration ability of the interstitial oxygen was very limited. |
format | Article |
fullrecord | <record><control><sourceid>pubmed</sourceid><recordid>TN_cdi_pubmed_primary_29882675</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>29882675</sourcerecordid><originalsourceid>FETCH-pubmed_primary_298826753</originalsourceid><addsrcrecordid>eNqFjktrAjEAhEOh-Kj-hTJ4UnRpNuv6QHrQxT4Oyx7Wg3iRaKJENEoeUv9Df3Rdbc89zTDzDcwDqYQxo0Ec0nmZVK3dUUqHUbdXImU2HAxYrx9XyHfuV9Yp55066uBTC7-WArkzfu28kZiej_tbB64FFhqsjZd3jqiNzAhplN5CaTTCsNtA9qWEtEjHBYcrxZChjyZSvCLhxbaD3BQ6wvia3X0Hk1vXqpHHDd9bWf_VJ_L8Np0lH8HJrw5SLE9GHbi5LP_uR_8CP72XRt4</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Substitution-Induced Structure Evolution and Zn 2+ /Ga 3+ Ordering in "114" Oxides MAZn 2 Ga 2 O 7 ( M = Ca 2+ , Sr 2+ ; A = Sr 2+ , Ba 2+ )</title><source>American Chemical Society Journals</source><creator>Jiang, Pengfei ; Huang, Qingzhen ; Avdeev, Maxim ; Tao, Fengqiong ; Zhou, Lijia ; Gao, Wenliang ; Cong, Rihong ; Yang, Tao</creator><creatorcontrib>Jiang, Pengfei ; Huang, Qingzhen ; Avdeev, Maxim ; Tao, Fengqiong ; Zhou, Lijia ; Gao, Wenliang ; Cong, Rihong ; Yang, Tao</creatorcontrib><description>The "114" oxides LnBa(Co/Fe)
O
represent a new family of materials that exhibits intriguing physical properties, including geometrically frustrated magnetism, oxygen storage, and magnetoelectric couplings. Various chemical substitutions have been conducted to modify their crystal and magnetic structures as well as physical properties. However, the principles beneath the substitution-induced structural evolution and charge/cationic ordering have not yet been understood. Thus, in this contribution, two complete solid solutions of MAZn
Ga
O
( M = Ca
, Sr
; A = Sr
, Ba
) were designed, synthesized, and characterized by Rietveld refinements based on high-resolution X-ray diffraction (XRD) and neutron diffraction (ND) data. The structure symmetry of MAZn
Ga
O
is determined by the cationic size mismatch between M and A cations that can be defined by the tolerance factor t, i.e., symmetry transitions from P6
mc ( t > 0.87) to P31 c (0.87 > t > 0.75) and to Pna2
( t < 0.75) were observed for MAZn
Ga
O
, associated with the rotation of T1O
tetrahedra in the triangular layers. The Zn
/Ga
ordering at T sites is also a consequence of the increase or decrease of the average sizes of M and A cations. A small concentration of interstitial oxygen ions can be obtained in Sr
Zn
Ga
O
( x = 0.1, 0.2); however, no oxygen ionic conduction was observed at high temperatures, indicating the migration ability of the interstitial oxygen was very limited.</description><identifier>EISSN: 1520-510X</identifier><identifier>PMID: 29882675</identifier><language>eng</language><publisher>United States</publisher><ispartof>Inorganic chemistry, 2018-06</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-6832-7462 ; 0000-0002-2276-4023 ; 0000-0002-9018-6819 ; 0000-0003-2366-5809</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29882675$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Jiang, Pengfei</creatorcontrib><creatorcontrib>Huang, Qingzhen</creatorcontrib><creatorcontrib>Avdeev, Maxim</creatorcontrib><creatorcontrib>Tao, Fengqiong</creatorcontrib><creatorcontrib>Zhou, Lijia</creatorcontrib><creatorcontrib>Gao, Wenliang</creatorcontrib><creatorcontrib>Cong, Rihong</creatorcontrib><creatorcontrib>Yang, Tao</creatorcontrib><title>Substitution-Induced Structure Evolution and Zn 2+ /Ga 3+ Ordering in "114" Oxides MAZn 2 Ga 2 O 7 ( M = Ca 2+ , Sr 2+ ; A = Sr 2+ , Ba 2+ )</title><title>Inorganic chemistry</title><addtitle>Inorg Chem</addtitle><description>The "114" oxides LnBa(Co/Fe)
O
represent a new family of materials that exhibits intriguing physical properties, including geometrically frustrated magnetism, oxygen storage, and magnetoelectric couplings. Various chemical substitutions have been conducted to modify their crystal and magnetic structures as well as physical properties. However, the principles beneath the substitution-induced structural evolution and charge/cationic ordering have not yet been understood. Thus, in this contribution, two complete solid solutions of MAZn
Ga
O
( M = Ca
, Sr
; A = Sr
, Ba
) were designed, synthesized, and characterized by Rietveld refinements based on high-resolution X-ray diffraction (XRD) and neutron diffraction (ND) data. The structure symmetry of MAZn
Ga
O
is determined by the cationic size mismatch between M and A cations that can be defined by the tolerance factor t, i.e., symmetry transitions from P6
mc ( t > 0.87) to P31 c (0.87 > t > 0.75) and to Pna2
( t < 0.75) were observed for MAZn
Ga
O
, associated with the rotation of T1O
tetrahedra in the triangular layers. The Zn
/Ga
ordering at T sites is also a consequence of the increase or decrease of the average sizes of M and A cations. A small concentration of interstitial oxygen ions can be obtained in Sr
Zn
Ga
O
( x = 0.1, 0.2); however, no oxygen ionic conduction was observed at high temperatures, indicating the migration ability of the interstitial oxygen was very limited.</description><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFjktrAjEAhEOh-Kj-hTJ4UnRpNuv6QHrQxT4Oyx7Wg3iRaKJENEoeUv9Df3Rdbc89zTDzDcwDqYQxo0Ec0nmZVK3dUUqHUbdXImU2HAxYrx9XyHfuV9Yp55066uBTC7-WArkzfu28kZiej_tbB64FFhqsjZd3jqiNzAhplN5CaTTCsNtA9qWEtEjHBYcrxZChjyZSvCLhxbaD3BQ6wvia3X0Hk1vXqpHHDd9bWf_VJ_L8Np0lH8HJrw5SLE9GHbi5LP_uR_8CP72XRt4</recordid><startdate>20180608</startdate><enddate>20180608</enddate><creator>Jiang, Pengfei</creator><creator>Huang, Qingzhen</creator><creator>Avdeev, Maxim</creator><creator>Tao, Fengqiong</creator><creator>Zhou, Lijia</creator><creator>Gao, Wenliang</creator><creator>Cong, Rihong</creator><creator>Yang, Tao</creator><scope>NPM</scope><orcidid>https://orcid.org/0000-0001-6832-7462</orcidid><orcidid>https://orcid.org/0000-0002-2276-4023</orcidid><orcidid>https://orcid.org/0000-0002-9018-6819</orcidid><orcidid>https://orcid.org/0000-0003-2366-5809</orcidid></search><sort><creationdate>20180608</creationdate><title>Substitution-Induced Structure Evolution and Zn 2+ /Ga 3+ Ordering in "114" Oxides MAZn 2 Ga 2 O 7 ( M = Ca 2+ , Sr 2+ ; A = Sr 2+ , Ba 2+ )</title><author>Jiang, Pengfei ; Huang, Qingzhen ; Avdeev, Maxim ; Tao, Fengqiong ; Zhou, Lijia ; Gao, Wenliang ; Cong, Rihong ; Yang, Tao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_298826753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jiang, Pengfei</creatorcontrib><creatorcontrib>Huang, Qingzhen</creatorcontrib><creatorcontrib>Avdeev, Maxim</creatorcontrib><creatorcontrib>Tao, Fengqiong</creatorcontrib><creatorcontrib>Zhou, Lijia</creatorcontrib><creatorcontrib>Gao, Wenliang</creatorcontrib><creatorcontrib>Cong, Rihong</creatorcontrib><creatorcontrib>Yang, Tao</creatorcontrib><collection>PubMed</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jiang, Pengfei</au><au>Huang, Qingzhen</au><au>Avdeev, Maxim</au><au>Tao, Fengqiong</au><au>Zhou, Lijia</au><au>Gao, Wenliang</au><au>Cong, Rihong</au><au>Yang, Tao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Substitution-Induced Structure Evolution and Zn 2+ /Ga 3+ Ordering in "114" Oxides MAZn 2 Ga 2 O 7 ( M = Ca 2+ , Sr 2+ ; A = Sr 2+ , Ba 2+ )</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg Chem</addtitle><date>2018-06-08</date><risdate>2018</risdate><eissn>1520-510X</eissn><abstract>The "114" oxides LnBa(Co/Fe)
O
represent a new family of materials that exhibits intriguing physical properties, including geometrically frustrated magnetism, oxygen storage, and magnetoelectric couplings. Various chemical substitutions have been conducted to modify their crystal and magnetic structures as well as physical properties. However, the principles beneath the substitution-induced structural evolution and charge/cationic ordering have not yet been understood. Thus, in this contribution, two complete solid solutions of MAZn
Ga
O
( M = Ca
, Sr
; A = Sr
, Ba
) were designed, synthesized, and characterized by Rietveld refinements based on high-resolution X-ray diffraction (XRD) and neutron diffraction (ND) data. The structure symmetry of MAZn
Ga
O
is determined by the cationic size mismatch between M and A cations that can be defined by the tolerance factor t, i.e., symmetry transitions from P6
mc ( t > 0.87) to P31 c (0.87 > t > 0.75) and to Pna2
( t < 0.75) were observed for MAZn
Ga
O
, associated with the rotation of T1O
tetrahedra in the triangular layers. The Zn
/Ga
ordering at T sites is also a consequence of the increase or decrease of the average sizes of M and A cations. A small concentration of interstitial oxygen ions can be obtained in Sr
Zn
Ga
O
( x = 0.1, 0.2); however, no oxygen ionic conduction was observed at high temperatures, indicating the migration ability of the interstitial oxygen was very limited.</abstract><cop>United States</cop><pmid>29882675</pmid><orcidid>https://orcid.org/0000-0001-6832-7462</orcidid><orcidid>https://orcid.org/0000-0002-2276-4023</orcidid><orcidid>https://orcid.org/0000-0002-9018-6819</orcidid><orcidid>https://orcid.org/0000-0003-2366-5809</orcidid></addata></record> |
fulltext | fulltext |
identifier | EISSN: 1520-510X |
ispartof | Inorganic chemistry, 2018-06 |
issn | 1520-510X |
language | eng |
recordid | cdi_pubmed_primary_29882675 |
source | American Chemical Society Journals |
title | Substitution-Induced Structure Evolution and Zn 2+ /Ga 3+ Ordering in "114" Oxides MAZn 2 Ga 2 O 7 ( M = Ca 2+ , Sr 2+ ; A = Sr 2+ , Ba 2+ ) |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T13%3A16%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Substitution-Induced%20Structure%20Evolution%20and%20Zn%202+%20/Ga%203+%20Ordering%20in%20%22114%22%20Oxides%20MAZn%202%20Ga%202%20O%207%20(%20M%20=%20Ca%202+%20,%20Sr%202+%20;%20A%20=%20Sr%202+%20,%20Ba%202+%20)&rft.jtitle=Inorganic%20chemistry&rft.au=Jiang,%20Pengfei&rft.date=2018-06-08&rft.eissn=1520-510X&rft_id=info:doi/&rft_dat=%3Cpubmed%3E29882675%3C/pubmed%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/29882675&rfr_iscdi=true |