A Balance Between van der Waals and Cation-π Interactions That Stabilizes Hydrophobic Assemblies

A thermally most stable molecular self-assembly in water (nanocube), whose decomposition temperature is 142 °C, has been developed by the design of a gear-shaped amphiphile (GSA) with an indented hydrophobic surface, even though the nanocube is stabilized only by van der Waals (vdW) and cation-pinte...

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Veröffentlicht in:	Chemistry : a European journal 2018-04
Hauptverfasser:	Zhan, Yi-Yan, Kojima, Tatsuo, Koide, Takuya, Tachikawa, Masanori, Hiraoka, Shuichi
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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