Mechanistic Investigation of Oxidative Decarboxylation Catalyzed by Two Iron(II)- and 2‑Oxoglutarate-Dependent Enzymes

Two non-heme iron enzymes, IsnB and AmbI3, catalyze a novel decarboxylation-assisted olefination to produce indole vinyl isonitrile, an important building block for many natural products. Compared to other reactions catalyzed by this enzyme family, decarboxylation-assisted olefination represents an...

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Veröffentlicht in:	Biochemistry (Easton) 2018-03, Vol.57 (12), p.1838-1841
Hauptverfasser:	Huang, Jhih-Liang, Tang, Yijie, Yu, Cheng-Ping, Sanyal, Dev, Jia, Xinglin, Liu, Xinyu, Guo, Yisong, Chang, Wei-chen
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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