Small endohedral metallofullerenes: exploration of the structure and growth mechanism in the Ti@C 2 n (2 n = 26-50) family

The formation of the smallest fullerene, C , was recently reported using gas phase experiments combined with high-resolution FT-ICR mass spectrometry. An internally located group IV metal stabilizes the highly strained non-IPR C cage by charge transfer (IPR = isolated pentagon rule). Ti@C also appea...

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Veröffentlicht in:	Chemical science (Cambridge) 2015-01, Vol.6 (1), p.675
Hauptverfasser:	Mulet-Gas, Marc, Abella, Laura, Dunk, Paul W, Rodríguez-Fortea, Antonio, Kroto, Harold W, Poblet, Josep M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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