Dynamic nuclear polarisation by thermal mixing: quantum theory and macroscopic simulations

A theory of dynamic nuclear polarisation (DNP) by thermal mixing is suggested based on purely quantum considerations. A minimal 6-level microscopic model is developed to test the theory and link it to the well-known thermodynamic model. Optimal conditions for the nuclear polarization enhancement and...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2016-11, Vol.18 (43), p.393-314
Hauptverfasser:	Karabanov, Alexander, Kwiatkowski, Grzegorz, Perotto, Carlo U, Wi niewski, Daniel, McMaster, Jonathan, Lesanovsky, Igor, Köckenberger, Walter
Format:	Artikel
Sprache:	eng
Schlagworte:	Computer simulation Dynamics Free radicals Optimization Physical chemistry Polarization Spectra Thermodynamic models
Online-Zugang:	Volltext
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