Rhodium(), rhodium() and iridium() carbaporphyrins
Treatment of a benzocarbaporphyrin with [Rh(CO) 2 Cl] 2 in refluxing dichloromethane gave a rhodium( i ) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium( iii ) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl] 2 and pyridine in refluxing p...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (35), p.13691-13694 |
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| container_end_page | 13694 |
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| container_issue | 35 |
| container_start_page | 13691 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 45 |
| creator | Adiraju, Venkata A. K Ferrence, Gregory M Lash, Timothy D |
| description | Treatment of a benzocarbaporphyrin with [Rh(CO)
2
Cl]
2
in refluxing dichloromethane gave a rhodium(
i
) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium(
iii
) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl]
2
and pyridine in refluxing
p
-xylene to generate a related iridium(
iii
) compound. These novel metalated porphyrinoids retained strongly diatropic characteristics and were fully characterized by XRD.
Reaction of a benzocarbaporphyrin with [Rh(CO)
2
Cl]
2
or [Ir(COD)Cl]
2
gave a rhodium(
i
) dicarbonyl complex and rhodium(
iii
) or iridium(
iii
) organometallic derivatives. |
| doi_str_mv | 10.1039/c6dt03093a |
| format | Article |
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2
Cl]
2
in refluxing dichloromethane gave a rhodium(
i
) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium(
iii
) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl]
2
and pyridine in refluxing
p
-xylene to generate a related iridium(
iii
) compound. These novel metalated porphyrinoids retained strongly diatropic characteristics and were fully characterized by XRD.
Reaction of a benzocarbaporphyrin with [Rh(CO)
2
Cl]
2
or [Ir(COD)Cl]
2
gave a rhodium(
i
) dicarbonyl complex and rhodium(
iii
) or iridium(
iii
) organometallic derivatives.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c6dt03093a</identifier><identifier>PMID: 27529466</identifier><language>eng</language><publisher>England</publisher><subject>Derivatives ; Dichloromethane ; Metalorganic compounds ; Pyridines ; Refluxing</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2016-01, Vol.45 (35), p.13691-13694</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c408t-7d7a7baeab77556ebf03af2dd5bc88860a21de52e2af1358d128efdca7cb33ef3</citedby><cites>FETCH-LOGICAL-c408t-7d7a7baeab77556ebf03af2dd5bc88860a21de52e2af1358d128efdca7cb33ef3</cites><orcidid>0000-0001-7549-3856 ; 0000-0001-6027-7288</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27529466$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Adiraju, Venkata A. K</creatorcontrib><creatorcontrib>Ferrence, Gregory M</creatorcontrib><creatorcontrib>Lash, Timothy D</creatorcontrib><title>Rhodium(), rhodium() and iridium() carbaporphyrins</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Treatment of a benzocarbaporphyrin with [Rh(CO)
2
Cl]
2
in refluxing dichloromethane gave a rhodium(
i
) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium(
iii
) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl]
2
and pyridine in refluxing
p
-xylene to generate a related iridium(
iii
) compound. These novel metalated porphyrinoids retained strongly diatropic characteristics and were fully characterized by XRD.
Reaction of a benzocarbaporphyrin with [Rh(CO)
2
Cl]
2
or [Ir(COD)Cl]
2
gave a rhodium(
i
) dicarbonyl complex and rhodium(
iii
) or iridium(
iii
) organometallic derivatives.</description><subject>Derivatives</subject><subject>Dichloromethane</subject><subject>Metalorganic compounds</subject><subject>Pyridines</subject><subject>Refluxing</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqNkTlPw0AQRlcIREKgoQelDAjD3rsuo3BKkZBQqK3ZSzGKY7NrF_n3CeSgpZpvNE9f8QahS4LvCWb5g5WuxQznDI5Qn3ClspwyfnzIVPbQWUpfGFOKBT1FPaoEzbmUfUQ_5rUru2p0czeM-ziEpRuWsdxtFqKBpo7NfBXLZTpHJwEWyV_s5gB9Pj_NJq_Z9P3lbTKeZpZj3WbKKVAGPBilhJDeBMwgUOeEsVpriYES5wX1FAJhQjtCtQ_OgrKGMR_YAI22vU2svzuf2qIqk_WLBSx93aWCaCYk50zpf6BE5EpwLDfo7Ra1sU4p-lA0sawgrgqCix-dxUQ-zn51jjfw9a63M5V3B3TvbwNcbYGY7OH69w-2ButTeIE</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Adiraju, Venkata A. K</creator><creator>Ferrence, Gregory M</creator><creator>Lash, Timothy D</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-7549-3856</orcidid><orcidid>https://orcid.org/0000-0001-6027-7288</orcidid></search><sort><creationdate>20160101</creationdate><title>Rhodium(), rhodium() and iridium() carbaporphyrins</title><author>Adiraju, Venkata A. K ; Ferrence, Gregory M ; Lash, Timothy D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-7d7a7baeab77556ebf03af2dd5bc88860a21de52e2af1358d128efdca7cb33ef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Derivatives</topic><topic>Dichloromethane</topic><topic>Metalorganic compounds</topic><topic>Pyridines</topic><topic>Refluxing</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adiraju, Venkata A. K</creatorcontrib><creatorcontrib>Ferrence, Gregory M</creatorcontrib><creatorcontrib>Lash, Timothy D</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adiraju, Venkata A. K</au><au>Ferrence, Gregory M</au><au>Lash, Timothy D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rhodium(), rhodium() and iridium() carbaporphyrins</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>45</volume><issue>35</issue><spage>13691</spage><epage>13694</epage><pages>13691-13694</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Treatment of a benzocarbaporphyrin with [Rh(CO)
2
Cl]
2
in refluxing dichloromethane gave a rhodium(
i
) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium(
iii
) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl]
2
and pyridine in refluxing
p
-xylene to generate a related iridium(
iii
) compound. These novel metalated porphyrinoids retained strongly diatropic characteristics and were fully characterized by XRD.
Reaction of a benzocarbaporphyrin with [Rh(CO)
2
Cl]
2
or [Ir(COD)Cl]
2
gave a rhodium(
i
) dicarbonyl complex and rhodium(
iii
) or iridium(
iii
) organometallic derivatives.</abstract><cop>England</cop><pmid>27529466</pmid><doi>10.1039/c6dt03093a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-7549-3856</orcidid><orcidid>https://orcid.org/0000-0001-6027-7288</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2016-01, Vol.45 (35), p.13691-13694 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_pubmed_primary_27529466 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Derivatives Dichloromethane Metalorganic compounds Pyridines Refluxing |
| title | Rhodium(), rhodium() and iridium() carbaporphyrins |
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