Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene

We have synthesized the first diamidocarbene (DAC)-supported borenium salt, [ 3 ][OTf], which was found to readily undergo two sequential 1-electron reductions. The first reduction forms a thermally robust, crystalline boryl-substituted DAC-centred radical ( 3&z.rad; ) which has been fully chara...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (24), p.982-9826
Hauptverfasser:	Ledet, Anthony D, Hudnall, Todd W
Format:	Artikel
Sprache:	eng
Schlagworte:	Cations Computation Crystal structure Formations NMR spectroscopy Radicals Reduction Spectroscopy
Online-Zugang:	Volltext
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