An efficient oxygen evolving catalyst based on a μ-O diiron coordination complex

A family of oxygen evolving catalysts was investigated, which was based on the most desired first-row transition metal iron. Among them, the highest turnover number of 2380 was obtained in acetate buffer at pH 4.5 with [(TPA) 2 Fe 2 (μ-O)(μ-OAc)] 3+ . An iron( iii ) complex, [(TPA) 2 Fe 2 (μ-O)(μ-OA...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2014-10, Vol.5 (84), p.12779-12782
Hauptverfasser:	Liu, Yongdong, Xiang, Rui, Du, Xiaoqiang, Ding, Yong, Ma, Baochun
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates Buffers (chemistry) Catalysts Iron Transition metals
Online-Zugang:	Volltext
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