An efficient oxygen evolving catalyst based on a μ-O diiron coordination complex
A family of oxygen evolving catalysts was investigated, which was based on the most desired first-row transition metal iron. Among them, the highest turnover number of 2380 was obtained in acetate buffer at pH 4.5 with [(TPA) 2 Fe 2 (μ-O)(μ-OAc)] 3+ . An iron( iii ) complex, [(TPA) 2 Fe 2 (μ-O)(μ-OA...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2014-10, Vol.5 (84), p.12779-12782 |
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| container_issue | 84 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Liu, Yongdong Xiang, Rui Du, Xiaoqiang Ding, Yong Ma, Baochun |
| description | A family of oxygen evolving catalysts was investigated, which was based on the most desired first-row transition metal iron. Among them, the highest turnover number of 2380 was obtained in acetate buffer at pH 4.5 with [(TPA)
2
Fe
2
(μ-O)(μ-OAc)]
3+
.
An iron(
iii
) complex, [(TPA)
2
Fe
2
(μ-O)(μ-OAc)]
3+
, containing a nitrogen ligand shows excellent activity towards oxygen evolution, yielding a high turnover number of 2380. |
| doi_str_mv | 10.1039/c4cc04118f |
| format | Article |
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2
Fe
2
(μ-O)(μ-OAc)]
3+
.
An iron(
iii
) complex, [(TPA)
2
Fe
2
(μ-O)(μ-OAc)]
3+
, containing a nitrogen ligand shows excellent activity towards oxygen evolution, yielding a high turnover number of 2380.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c4cc04118f</identifier><identifier>PMID: 25208826</identifier><language>eng</language><publisher>England</publisher><subject>Acetates ; Buffers (chemistry) ; Catalysts ; Iron ; Transition metals</subject><ispartof>Chemical communications (Cambridge, England), 2014-10, Vol.5 (84), p.12779-12782</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-b63ac0b43f49a9365cc6558e79ee44adf950c25d88200c78ff367425cb6595483</citedby><cites>FETCH-LOGICAL-c368t-b63ac0b43f49a9365cc6558e79ee44adf950c25d88200c78ff367425cb6595483</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25208826$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Yongdong</creatorcontrib><creatorcontrib>Xiang, Rui</creatorcontrib><creatorcontrib>Du, Xiaoqiang</creatorcontrib><creatorcontrib>Ding, Yong</creatorcontrib><creatorcontrib>Ma, Baochun</creatorcontrib><title>An efficient oxygen evolving catalyst based on a μ-O diiron coordination complex</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>A family of oxygen evolving catalysts was investigated, which was based on the most desired first-row transition metal iron. Among them, the highest turnover number of 2380 was obtained in acetate buffer at pH 4.5 with [(TPA)
2
Fe
2
(μ-O)(μ-OAc)]
3+
.
An iron(
iii
) complex, [(TPA)
2
Fe
2
(μ-O)(μ-OAc)]
3+
, containing a nitrogen ligand shows excellent activity towards oxygen evolution, yielding a high turnover number of 2380.</description><subject>Acetates</subject><subject>Buffers (chemistry)</subject><subject>Catalysts</subject><subject>Iron</subject><subject>Transition metals</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkc1KAzEUhYMotlY37pVxJ8JoMvmZzLIMVoVCERTcDZlMUiIzk5pMS_tuPoPPZPpj3end5N6cj0PuCQDnCN4iiLM7SaSEBCGuD0AfYUZiSvjb4bqnWZxiQnvgxPt3GApRfgx6CU0g5wnrg-dhGymtjTSq7SK7XE1VuFjYemHaaSRFJ-qV76JSeFVFto1E9PUZT6LKGBcmaa2rTCs6sxmaWa2Wp-BIi9qrs905AK-j-5f8MR5PHp7y4TiWmPEuLhkWEpYEa5KJDDMqJaOUqzRTihBR6YxCmdAqPBNCmXKtMUtJQmXJaBb2wwNwvfWdOfsxV74rGuOlqmvRKjv3BWIpYihsT_5HKWMIpihdozdbVDrrvVO6mDnTCLcqECzWaRc5yfNN2qMAX-5852Wjqj36E28ALraA83Kv_n5X0K_-0otZpfE3v3OO6g</recordid><startdate>20141028</startdate><enddate>20141028</enddate><creator>Liu, Yongdong</creator><creator>Xiang, Rui</creator><creator>Du, Xiaoqiang</creator><creator>Ding, Yong</creator><creator>Ma, Baochun</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20141028</creationdate><title>An efficient oxygen evolving catalyst based on a μ-O diiron coordination complex</title><author>Liu, Yongdong ; Xiang, Rui ; Du, Xiaoqiang ; Ding, Yong ; Ma, Baochun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-b63ac0b43f49a9365cc6558e79ee44adf950c25d88200c78ff367425cb6595483</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Acetates</topic><topic>Buffers (chemistry)</topic><topic>Catalysts</topic><topic>Iron</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Yongdong</creatorcontrib><creatorcontrib>Xiang, Rui</creatorcontrib><creatorcontrib>Du, Xiaoqiang</creatorcontrib><creatorcontrib>Ding, Yong</creatorcontrib><creatorcontrib>Ma, Baochun</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Yongdong</au><au>Xiang, Rui</au><au>Du, Xiaoqiang</au><au>Ding, Yong</au><au>Ma, Baochun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An efficient oxygen evolving catalyst based on a μ-O diiron coordination complex</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2014-10-28</date><risdate>2014</risdate><volume>5</volume><issue>84</issue><spage>12779</spage><epage>12782</epage><pages>12779-12782</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A family of oxygen evolving catalysts was investigated, which was based on the most desired first-row transition metal iron. Among them, the highest turnover number of 2380 was obtained in acetate buffer at pH 4.5 with [(TPA)
2
Fe
2
(μ-O)(μ-OAc)]
3+
.
An iron(
iii
) complex, [(TPA)
2
Fe
2
(μ-O)(μ-OAc)]
3+
, containing a nitrogen ligand shows excellent activity towards oxygen evolution, yielding a high turnover number of 2380.</abstract><cop>England</cop><pmid>25208826</pmid><doi>10.1039/c4cc04118f</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2014-10, Vol.5 (84), p.12779-12782 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_pubmed_primary_25208826 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acetates Buffers (chemistry) Catalysts Iron Transition metals |
| title | An efficient oxygen evolving catalyst based on a μ-O diiron coordination complex |
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