Fullerene-porphyrin supramolecular nanocables
Novel fullerene-porphyrin supramolecular nanocables were designed and their electronic properties were studied using computational modeling and first-principles density functional theory. It is demonstrated that two well-defined fullerene-porphyrin nanocables have clear channels for charge transport...
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| Veröffentlicht in: | Nanotechnology 2014-06, Vol.25 (23), p.235201-4 |
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| creator | Buldum, A Reneker, D H |
| description | Novel fullerene-porphyrin supramolecular nanocables were designed and their electronic properties were studied using computational modeling and first-principles density functional theory. It is demonstrated that two well-defined fullerene-porphyrin nanocables have clear channels for charge transport by electrons and holes. These two interesting nanocables have zigzag or helical chains of molecules around a -stacked porphyrin core. They also have frontier electronic states which are spatially extended along the axes of the nanocables. Ballistic electronic transport is possible for ultrafast transfer of electrons along chains. We believe these supramolecular nanocables can play important roles in molecular electronics, optoelectronics and photovoltaics. |
| doi_str_mv | 10.1088/0957-4484/25/23/235201 |
| format | Article |
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It is demonstrated that two well-defined fullerene-porphyrin nanocables have clear channels for charge transport by electrons and holes. These two interesting nanocables have zigzag or helical chains of molecules around a -stacked porphyrin core. They also have frontier electronic states which are spatially extended along the axes of the nanocables. Ballistic electronic transport is possible for ultrafast transfer of electrons along chains. We believe these supramolecular nanocables can play important roles in molecular electronics, optoelectronics and photovoltaics.</description><identifier>ISSN: 0957-4484</identifier><identifier>EISSN: 1361-6528</identifier><identifier>DOI: 10.1088/0957-4484/25/23/235201</identifier><identifier>PMID: 24849532</identifier><identifier>CODEN: NNOTER</identifier><language>eng</language><publisher>Bristol: IOP Publishing</publisher><subject>Buckminsterfullerene ; Channels ; Charge transport ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Cross-disciplinary physics: materials science; rheology ; Electron states ; Electron states and collective excitations in thin films, multilayers, quantum wells, mesoscopic and nanoscale systems ; Electron Transport ; Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures ; Electronic transport in multilayers, nanoscale materials and structures ; Electronics ; Electrons ; Energy Transfer ; Exact sciences and technology ; Fullerenes ; Fullerenes - chemistry ; Fullerenes and related materials; diamonds, graphite ; Humans ; Materials science ; Metalloporphyrins - chemistry ; Methods of electronic structure calculations ; Models, Biological ; molecular electronics ; Molecular Structure ; nanocables ; Nanostructure ; Nanotechnology ; Nanotubes, Carbon - chemistry ; nanowires ; photovoltaics ; Physics ; simulations ; Solar cells ; Specific materials</subject><ispartof>Nanotechnology, 2014-06, Vol.25 (23), p.235201-4</ispartof><rights>2014 IOP Publishing Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c484t-bed1ddcd7519c26665baedd130b1d429af4be21f2dc551854c0da9d53d6121c23</citedby><cites>FETCH-LOGICAL-c484t-bed1ddcd7519c26665baedd130b1d429af4be21f2dc551854c0da9d53d6121c23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1088/0957-4484/25/23/235201/pdf$$EPDF$$P50$$Giop$$H</linktopdf><link.rule.ids>314,780,784,27924,27925,53846,53893</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28506933$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24849532$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Buldum, A</creatorcontrib><creatorcontrib>Reneker, D H</creatorcontrib><title>Fullerene-porphyrin supramolecular nanocables</title><title>Nanotechnology</title><addtitle>NANO</addtitle><addtitle>Nanotechnology</addtitle><description>Novel fullerene-porphyrin supramolecular nanocables were designed and their electronic properties were studied using computational modeling and first-principles density functional theory. It is demonstrated that two well-defined fullerene-porphyrin nanocables have clear channels for charge transport by electrons and holes. These two interesting nanocables have zigzag or helical chains of molecules around a -stacked porphyrin core. They also have frontier electronic states which are spatially extended along the axes of the nanocables. Ballistic electronic transport is possible for ultrafast transfer of electrons along chains. We believe these supramolecular nanocables can play important roles in molecular electronics, optoelectronics and photovoltaics.</description><subject>Buckminsterfullerene</subject><subject>Channels</subject><subject>Charge transport</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Electron states</subject><subject>Electron states and collective excitations in thin films, multilayers, quantum wells, mesoscopic and nanoscale systems</subject><subject>Electron Transport</subject><subject>Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures</subject><subject>Electronic transport in multilayers, nanoscale materials and structures</subject><subject>Electronics</subject><subject>Electrons</subject><subject>Energy Transfer</subject><subject>Exact sciences and technology</subject><subject>Fullerenes</subject><subject>Fullerenes - chemistry</subject><subject>Fullerenes and related materials; diamonds, graphite</subject><subject>Humans</subject><subject>Materials science</subject><subject>Metalloporphyrins - chemistry</subject><subject>Methods of electronic structure calculations</subject><subject>Models, Biological</subject><subject>molecular electronics</subject><subject>Molecular Structure</subject><subject>nanocables</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Nanotubes, Carbon - chemistry</subject><subject>nanowires</subject><subject>photovoltaics</subject><subject>Physics</subject><subject>simulations</subject><subject>Solar cells</subject><subject>Specific materials</subject><issn>0957-4484</issn><issn>1361-6528</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqN0U1LwzAYB_Agis7pV5BdBD3U5XnSpMlxiFNh6EXPIU1SrGRtTdaD396WTUUQFAKB8Hte-IeQM6BXQKWcU8WLLM9lPkc-RzYcjhT2yASYgExwlPtk8oWOyHFKr5QCSIRDcoTDm-IMJyRb9iH46BufdW3sXt5j3cxS30WzboO3fTBx1pimtaYMPp2Qg8qE5E9395Q8L2-eru-y1ePt_fVildmh8SYrvQPnrCs4KItCCF4a7xwwWoLLUZkqLz1Chc5yDpLnljqjHGdOAIJFNiUX275dbN96nzZ6XSfrQzCNb_ukQRSFkpIJ8TfloqBcsYL9gzKVCywKGKjYUhvblKKvdBfrtYnvGqgeP0CP2eoxW41cI9PbDxgKz3Yz-nLt3VfZZ-IDON8Bk6wJVTSNrdO3k5wKxcZlL7eubjv92vaxGQLXD4uHxx8DdeeqweIv9o9NPwAxgKi6</recordid><startdate>20140613</startdate><enddate>20140613</enddate><creator>Buldum, A</creator><creator>Reneker, D H</creator><general>IOP Publishing</general><general>Institute of Physics</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140613</creationdate><title>Fullerene-porphyrin supramolecular nanocables</title><author>Buldum, A ; Reneker, D H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c484t-bed1ddcd7519c26665baedd130b1d429af4be21f2dc551854c0da9d53d6121c23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Buckminsterfullerene</topic><topic>Channels</topic><topic>Charge transport</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Electron states</topic><topic>Electron states and collective excitations in thin films, multilayers, quantum wells, mesoscopic and nanoscale systems</topic><topic>Electron Transport</topic><topic>Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures</topic><topic>Electronic transport in multilayers, nanoscale materials and structures</topic><topic>Electronics</topic><topic>Electrons</topic><topic>Energy Transfer</topic><topic>Exact sciences and technology</topic><topic>Fullerenes</topic><topic>Fullerenes - chemistry</topic><topic>Fullerenes and related materials; diamonds, graphite</topic><topic>Humans</topic><topic>Materials science</topic><topic>Metalloporphyrins - chemistry</topic><topic>Methods of electronic structure calculations</topic><topic>Models, Biological</topic><topic>molecular electronics</topic><topic>Molecular Structure</topic><topic>nanocables</topic><topic>Nanostructure</topic><topic>Nanotechnology</topic><topic>Nanotubes, Carbon - chemistry</topic><topic>nanowires</topic><topic>photovoltaics</topic><topic>Physics</topic><topic>simulations</topic><topic>Solar cells</topic><topic>Specific materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Buldum, A</creatorcontrib><creatorcontrib>Reneker, D H</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Nanotechnology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Buldum, A</au><au>Reneker, D H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fullerene-porphyrin supramolecular nanocables</atitle><jtitle>Nanotechnology</jtitle><stitle>NANO</stitle><addtitle>Nanotechnology</addtitle><date>2014-06-13</date><risdate>2014</risdate><volume>25</volume><issue>23</issue><spage>235201</spage><epage>4</epage><pages>235201-4</pages><issn>0957-4484</issn><eissn>1361-6528</eissn><coden>NNOTER</coden><abstract>Novel fullerene-porphyrin supramolecular nanocables were designed and their electronic properties were studied using computational modeling and first-principles density functional theory. It is demonstrated that two well-defined fullerene-porphyrin nanocables have clear channels for charge transport by electrons and holes. These two interesting nanocables have zigzag or helical chains of molecules around a -stacked porphyrin core. They also have frontier electronic states which are spatially extended along the axes of the nanocables. Ballistic electronic transport is possible for ultrafast transfer of electrons along chains. We believe these supramolecular nanocables can play important roles in molecular electronics, optoelectronics and photovoltaics.</abstract><cop>Bristol</cop><pub>IOP Publishing</pub><pmid>24849532</pmid><doi>10.1088/0957-4484/25/23/235201</doi><tpages>4</tpages></addata></record> |
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| subjects | Buckminsterfullerene Channels Charge transport Condensed matter: electronic structure, electrical, magnetic, and optical properties Cross-disciplinary physics: materials science rheology Electron states Electron states and collective excitations in thin films, multilayers, quantum wells, mesoscopic and nanoscale systems Electron Transport Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures Electronic transport in multilayers, nanoscale materials and structures Electronics Electrons Energy Transfer Exact sciences and technology Fullerenes Fullerenes - chemistry Fullerenes and related materials diamonds, graphite Humans Materials science Metalloporphyrins - chemistry Methods of electronic structure calculations Models, Biological molecular electronics Molecular Structure nanocables Nanostructure Nanotechnology Nanotubes, Carbon - chemistry nanowires photovoltaics Physics simulations Solar cells Specific materials |
| title | Fullerene-porphyrin supramolecular nanocables |
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