Effects of Al substitution and thermal annealing on magnetoelectric Ba0.5Sr1.5Zn2Fe12O22 investigated by the enhancement factor of 57Fe nuclear magnetic resonance

The magnetoelectric properties of hexaferrite Ba0.5Sr1.5Zn2Fe12O22 are significantly improved by Al substitution and thermal annealing. Measuring the enhancement factor of 57Fe NMR, we found direct microscopic evidence that the magnetic moments of the L and S blocks are rotated by a magnetic field i...

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Veröffentlicht in:Journal of physics. Condensed matter 2014-04, Vol.26 (14), p.146004-146004
Hauptverfasser: Kwon, Sangil, Kang, Byeongki, Kim, Changsoo, Jo, Euna, Lee, Soonchil, Chai, Yi Sheng, Chun, Sae Hwan, Kim, Kee Hoon
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container_end_page 146004
container_issue 14
container_start_page 146004
container_title Journal of physics. Condensed matter
container_volume 26
creator Kwon, Sangil
Kang, Byeongki
Kim, Changsoo
Jo, Euna
Lee, Soonchil
Chai, Yi Sheng
Chun, Sae Hwan
Kim, Kee Hoon
description The magnetoelectric properties of hexaferrite Ba0.5Sr1.5Zn2Fe12O22 are significantly improved by Al substitution and thermal annealing. Measuring the enhancement factor of 57Fe NMR, we found direct microscopic evidence that the magnetic moments of the L and S blocks are rotated by a magnetic field in such a way as to increase the net magnetic moment of a magnetic unit, even after the field is removed. Al substitution makes magnetoelectric property arise easily by suppressing the easy-plane anisotropy. The effect of thermal annealing is to stabilize the multiferroic state by reducing the number of pinning sites and the electron spin fluctuation. The transverse conic structure gradually changes to the alternating longitudinal conic structure where spins fluctuate more severely.
doi_str_mv 10.1088/0953-8984/26/14/146004
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subjects Aluminum - chemistry
Barium - chemistry
Electricity
enhancement factor
Ferric Compounds - chemistry
hexaferrites
Iron Radioisotopes - chemistry
Magnetic Resonance Spectroscopy
Magnetics
Models, Molecular
multiferroics
nuclear magnetic resonance
Strontium - chemistry
Temperature
Zinc - chemistry
title Effects of Al substitution and thermal annealing on magnetoelectric Ba0.5Sr1.5Zn2Fe12O22 investigated by the enhancement factor of 57Fe nuclear magnetic resonance
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