Degradation of the Persistent Organic Pollutant [14C]Heptachlor in Japanese Field Soils
The fate of [ 14 C]heptachlor in Saitama soil and the degradation of [ 14 C]heptachlor in four Japanese field soils over 112 d after application were investigated. Heptachlor was degraded mainly to cis-heptachlor epoxide by a biotic process and to 1-hydroxychlordene by an abiotic process in the fiel...
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| Veröffentlicht in: | Bioscience, biotechnology, and biochemistry biotechnology, and biochemistry, 2013, Vol.77 (6), p.1240-1244 |
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| container_title | Bioscience, biotechnology, and biochemistry |
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| creator | HAYASHI, Osamu KAMESHIRO, Maiko SATOH, Kiyoshi |
| description | The fate of [
14
C]heptachlor in Saitama soil and the degradation of [
14
C]heptachlor in four Japanese field soils over 112 d after application were investigated. Heptachlor was degraded mainly to cis-heptachlor epoxide by a biotic process and to 1-hydroxychlordene by an abiotic process in the field soils. Volatilization of heptachlor and cis-heptachlor epoxide from the soil was observed over the experimental period. The amount of 1-hydroxychlordene produced in the soils appeared to be related to the soil water contents. Because heptachlor and heptachlor epoxides are predicted to volatilize to the atmosphere and to persist in soils, these compounds are thought to spread among Japanese environmental compartments even after a ban on their use. |
| doi_str_mv | 10.1271/bbb.130017 |
| format | Article |
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14
C]heptachlor in Saitama soil and the degradation of [
14
C]heptachlor in four Japanese field soils over 112 d after application were investigated. Heptachlor was degraded mainly to cis-heptachlor epoxide by a biotic process and to 1-hydroxychlordene by an abiotic process in the field soils. Volatilization of heptachlor and cis-heptachlor epoxide from the soil was observed over the experimental period. The amount of 1-hydroxychlordene produced in the soils appeared to be related to the soil water contents. Because heptachlor and heptachlor epoxides are predicted to volatilize to the atmosphere and to persist in soils, these compounds are thought to spread among Japanese environmental compartments even after a ban on their use.</description><identifier>ISSN: 0916-8451</identifier><identifier>EISSN: 1347-6947</identifier><identifier>DOI: 10.1271/bbb.130017</identifier><identifier>PMID: 23748788</identifier><language>eng</language><publisher>England: Japan Society for Bioscience, Biotechnology, and Agrochemistry</publisher><subject>1-hydroxyhlordne ; Atmospheres ; Biochemistry ; Biodegradation, Environmental ; Biotechnology ; Carbon Radioisotopes - chemistry ; Carbon Radioisotopes - toxicity ; compartment model ; Compartments ; Degradation ; double first-order in parallel ; Epoxy Compounds - chemistry ; heptachlor ; Heptachlor - chemistry ; Heptachlor - toxicity ; heptachlor epoxide ; Heptachlor Epoxide - chemistry ; Indenes - chemistry ; Moisture content ; Pollutants ; Soil Pollutants, Radioactive ; Soils ; Spreads ; Volatilization ; Water - chemistry</subject><ispartof>Bioscience, biotechnology, and biochemistry, 2013, Vol.77 (6), p.1240-1244</ispartof><rights>2013 by Japan Society for Bioscience, Biotechnology, and Agrochemistry 2013</rights><rights>Copyright Japan Science and Technology Agency 2013</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c657t-f505587a81086f1ee8fd7d6ccca169006decd919f8e9225aff64a0ae93cfbffd3</citedby><cites>FETCH-LOGICAL-c657t-f505587a81086f1ee8fd7d6ccca169006decd919f8e9225aff64a0ae93cfbffd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4009,27902,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23748788$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>HAYASHI, Osamu</creatorcontrib><creatorcontrib>KAMESHIRO, Maiko</creatorcontrib><creatorcontrib>SATOH, Kiyoshi</creatorcontrib><title>Degradation of the Persistent Organic Pollutant [14C]Heptachlor in Japanese Field Soils</title><title>Bioscience, biotechnology, and biochemistry</title><addtitle>Biosci Biotechnol Biochem</addtitle><description>The fate of [
14
C]heptachlor in Saitama soil and the degradation of [
14
C]heptachlor in four Japanese field soils over 112 d after application were investigated. Heptachlor was degraded mainly to cis-heptachlor epoxide by a biotic process and to 1-hydroxychlordene by an abiotic process in the field soils. Volatilization of heptachlor and cis-heptachlor epoxide from the soil was observed over the experimental period. The amount of 1-hydroxychlordene produced in the soils appeared to be related to the soil water contents. Because heptachlor and heptachlor epoxides are predicted to volatilize to the atmosphere and to persist in soils, these compounds are thought to spread among Japanese environmental compartments even after a ban on their use.</description><subject>1-hydroxyhlordne</subject><subject>Atmospheres</subject><subject>Biochemistry</subject><subject>Biodegradation, Environmental</subject><subject>Biotechnology</subject><subject>Carbon Radioisotopes - chemistry</subject><subject>Carbon Radioisotopes - toxicity</subject><subject>compartment model</subject><subject>Compartments</subject><subject>Degradation</subject><subject>double first-order in parallel</subject><subject>Epoxy Compounds - chemistry</subject><subject>heptachlor</subject><subject>Heptachlor - chemistry</subject><subject>Heptachlor - toxicity</subject><subject>heptachlor epoxide</subject><subject>Heptachlor Epoxide - chemistry</subject><subject>Indenes - chemistry</subject><subject>Moisture content</subject><subject>Pollutants</subject><subject>Soil Pollutants, Radioactive</subject><subject>Soils</subject><subject>Spreads</subject><subject>Volatilization</subject><subject>Water - chemistry</subject><issn>0916-8451</issn><issn>1347-6947</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqN0U1rFTEUBuAgir2tbvwBMuBGClNzJp-zlGtrLYUWVFyIhEw-2pTcyW2SofTfG7nVRRF0FTg8vJyTF6FXgI9gEPBumqYjIBiDeIJWQKjo-UjFU7TCI_BeUgZ7aL-UG4zbgMFztDcQQaWQcoW-fXBXWVtdQ5q75Lt67bpLl0so1c21u8hXeg6mu0wxLlW3yXeg6x-nblu1uY4pd2HuzvRWz6647iS4aLvPKcTyAj3zOhb38uE9QF9Pjr-sT_vzi4-f1u_Pe8OZqL1nmDEptAQsuQfnpLfCcmOMBj5izK0zdoTRSzcOA9Pec6qxdiMxfvLekgP0dpe7zel2caWqTSjGxdg2SktRwHlLoYzDf1Aq2g9JQv9NiRiwBEJwo28e0Zu05LndrIAKiQcAMTZ1uFMmp1Ky82qbw0bnewVY_SpRtRLVrsSGXz9ELtPG2T_0d2sNsB0Is095o-9SjlZVfd8K8VnPJhRF_hL8E8YQqAk</recordid><startdate>2013</startdate><enddate>2013</enddate><creator>HAYASHI, Osamu</creator><creator>KAMESHIRO, Maiko</creator><creator>SATOH, Kiyoshi</creator><general>Japan Society for Bioscience, Biotechnology, and Agrochemistry</general><general>Oxford University Press</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7QO</scope><scope>7TV</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>7SU</scope><scope>7TB</scope><scope>7U5</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>2013</creationdate><title>Degradation of the Persistent Organic Pollutant [14C]Heptachlor in Japanese Field Soils</title><author>HAYASHI, Osamu ; KAMESHIRO, Maiko ; SATOH, Kiyoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c657t-f505587a81086f1ee8fd7d6ccca169006decd919f8e9225aff64a0ae93cfbffd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>1-hydroxyhlordne</topic><topic>Atmospheres</topic><topic>Biochemistry</topic><topic>Biodegradation, Environmental</topic><topic>Biotechnology</topic><topic>Carbon Radioisotopes - chemistry</topic><topic>Carbon Radioisotopes - toxicity</topic><topic>compartment model</topic><topic>Compartments</topic><topic>Degradation</topic><topic>double first-order in parallel</topic><topic>Epoxy Compounds - chemistry</topic><topic>heptachlor</topic><topic>Heptachlor - chemistry</topic><topic>Heptachlor - toxicity</topic><topic>heptachlor epoxide</topic><topic>Heptachlor Epoxide - chemistry</topic><topic>Indenes - chemistry</topic><topic>Moisture content</topic><topic>Pollutants</topic><topic>Soil Pollutants, Radioactive</topic><topic>Soils</topic><topic>Spreads</topic><topic>Volatilization</topic><topic>Water - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>HAYASHI, Osamu</creatorcontrib><creatorcontrib>KAMESHIRO, Maiko</creatorcontrib><creatorcontrib>SATOH, Kiyoshi</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Biotechnology Research Abstracts</collection><collection>Pollution Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Bioscience, biotechnology, and biochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>HAYASHI, Osamu</au><au>KAMESHIRO, Maiko</au><au>SATOH, Kiyoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Degradation of the Persistent Organic Pollutant [14C]Heptachlor in Japanese Field Soils</atitle><jtitle>Bioscience, biotechnology, and biochemistry</jtitle><addtitle>Biosci Biotechnol Biochem</addtitle><date>2013</date><risdate>2013</risdate><volume>77</volume><issue>6</issue><spage>1240</spage><epage>1244</epage><pages>1240-1244</pages><issn>0916-8451</issn><eissn>1347-6947</eissn><abstract>The fate of [
14
C]heptachlor in Saitama soil and the degradation of [
14
C]heptachlor in four Japanese field soils over 112 d after application were investigated. Heptachlor was degraded mainly to cis-heptachlor epoxide by a biotic process and to 1-hydroxychlordene by an abiotic process in the field soils. Volatilization of heptachlor and cis-heptachlor epoxide from the soil was observed over the experimental period. The amount of 1-hydroxychlordene produced in the soils appeared to be related to the soil water contents. Because heptachlor and heptachlor epoxides are predicted to volatilize to the atmosphere and to persist in soils, these compounds are thought to spread among Japanese environmental compartments even after a ban on their use.</abstract><cop>England</cop><pub>Japan Society for Bioscience, Biotechnology, and Agrochemistry</pub><pmid>23748788</pmid><doi>10.1271/bbb.130017</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | 1-hydroxyhlordne Atmospheres Biochemistry Biodegradation, Environmental Biotechnology Carbon Radioisotopes - chemistry Carbon Radioisotopes - toxicity compartment model Compartments Degradation double first-order in parallel Epoxy Compounds - chemistry heptachlor Heptachlor - chemistry Heptachlor - toxicity heptachlor epoxide Heptachlor Epoxide - chemistry Indenes - chemistry Moisture content Pollutants Soil Pollutants, Radioactive Soils Spreads Volatilization Water - chemistry |
| title | Degradation of the Persistent Organic Pollutant [14C]Heptachlor in Japanese Field Soils |
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