Effects of rare-earth co-doping on the local structure of rare-earth phosphate glasses using high and low energy X-ray diffraction

Rare-earth co-doping in inorganic materials has a long-held tradition of facilitating highly desirable optoelectronic properties for their application to the laser industry. This study concentrates specifically on rare-earth phosphate glasses, (R 2 O 3 ) x (R 2 O 3 ) y (P 2 O 5 ) 1( x + y ) , where...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Physical chemistry chemical physics : PCCP 2013-06, Vol.15 (22), p.8529-8543
Hauptverfasser: Cramer, Alisha J, Cole, Jacqueline M, FitzGerald, Vicky, Honkimaki, Veijo, Roberts, Mark A, Brennan, Tessa, Martin, Richard A, Saunders, George A, Newport, Robert J
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 8543
container_issue 22
container_start_page 8529
container_title Physical chemistry chemical physics : PCCP
container_volume 15
creator Cramer, Alisha J
Cole, Jacqueline M
FitzGerald, Vicky
Honkimaki, Veijo
Roberts, Mark A
Brennan, Tessa
Martin, Richard A
Saunders, George A
Newport, Robert J
description Rare-earth co-doping in inorganic materials has a long-held tradition of facilitating highly desirable optoelectronic properties for their application to the laser industry. This study concentrates specifically on rare-earth phosphate glasses, (R 2 O 3 ) x (R 2 O 3 ) y (P 2 O 5 ) 1( x + y ) , where (R, R) denotes (Ce, Er) or (La, Nd) co-doping and the total rare-earth composition corresponds to a range between metaphosphate, RP 3 O 9 , and ultraphosphate, RP 5 O 14 . Thereupon, the effects of rare-earth co-doping on the local structure are assessed at the atomic level. Pair-distribution function analysis of high-energy X-ray diffraction data ( Q max = 28 1 ) is employed to make this assessment. Results reveal a stark structural invariance to rare-earth co-doping which bears testament to the open-framework and rigid nature of these glasses. A range of desirable attributes of these glasses unfold from this finding; in particular, a structural simplicity that will enable facile molecular engineering of rare-earth phosphate glasses with dial-up lasing properties. When considered together with other factors, this finding also demonstrates additional prospects for these co-doped rare-earth phosphate glasses in nuclear waste storage applications. This study also reveals, for the first time, the ability to distinguish between PO and P&z.dbd;O bonding in these rare-earth phosphate glasses from X-ray diffraction data in a fully quantitative manner. Complementary analysis of high-energy X-ray diffraction data on single rare-earth phosphate glasses of similar rare-earth composition to the co-doped materials is also presented in this context. In a technical sense, all high-energy X-ray diffraction data on these glasses are compared with analogous low-energy diffraction data; their salient differences reveal distinct advantages of high-energy X-ray diffraction data for the study of amorphous materials. Rare-earth co-doping in inorganic materials has a long-held tradition of facilitating highly desirable optoelectronic properties for their application to the laser industry.
doi_str_mv 10.1039/c3cp44298e
format Article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmed_primary_23518599</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1353045193</sourcerecordid><originalsourceid>FETCH-LOGICAL-c434t-1f2abf5b6a2af4f1c5f5ec01f2259aa8cb17cacde0a5cb642f3fa1f4d4fb402d3</originalsourceid><addsrcrecordid>eNqF0UGL1TAQAOAgiruuXrwr8SCIUE2apO_luCy7Kix4UfBWptPJa6WvqZmU5V395fbxnm_Rg54yZL6ZgRkhnmv1Tivj36PBydrSr-mBONe2MoVXa_vwFK-qM_GE-btSSjttHouz0ji9dt6fi5_XIRBmljHIBIkKgpQ7ibFo49SPGxlHmTuSQ0QYJOc0Y54T_cWnLvLUQSa5GYCZWM68L-76TSdhbJfyO0kjpc1OfisS7GTbh5AAcx_Hp-JRgIHp2fG9EF9vrr9cfSxuP3_4dHV5W6A1Nhc6lNAE11RQQrBBowuOUC3fpfMAa2z0CgFbUuCwqWwZTAAdbGtDY1XZmgvx5tB3SvHHTJzrbc9IwwAjxZlr7aqV8r605v_UOKOs035P3x4opsicKNRT6reQdrVW9f489f15Fvzy2HduttSe6O97LOD1EQAvC19WNGLP925lvPFqP_XFwSXGU_aPQa_-la-nNphfTH2v2g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1353045193</pqid></control><display><type>article</type><title>Effects of rare-earth co-doping on the local structure of rare-earth phosphate glasses using high and low energy X-ray diffraction</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Cramer, Alisha J ; Cole, Jacqueline M ; FitzGerald, Vicky ; Honkimaki, Veijo ; Roberts, Mark A ; Brennan, Tessa ; Martin, Richard A ; Saunders, George A ; Newport, Robert J</creator><creatorcontrib>Cramer, Alisha J ; Cole, Jacqueline M ; FitzGerald, Vicky ; Honkimaki, Veijo ; Roberts, Mark A ; Brennan, Tessa ; Martin, Richard A ; Saunders, George A ; Newport, Robert J</creatorcontrib><description>Rare-earth co-doping in inorganic materials has a long-held tradition of facilitating highly desirable optoelectronic properties for their application to the laser industry. This study concentrates specifically on rare-earth phosphate glasses, (R 2 O 3 ) x (R 2 O 3 ) y (P 2 O 5 ) 1( x + y ) , where (R, R) denotes (Ce, Er) or (La, Nd) co-doping and the total rare-earth composition corresponds to a range between metaphosphate, RP 3 O 9 , and ultraphosphate, RP 5 O 14 . Thereupon, the effects of rare-earth co-doping on the local structure are assessed at the atomic level. Pair-distribution function analysis of high-energy X-ray diffraction data ( Q max = 28 1 ) is employed to make this assessment. Results reveal a stark structural invariance to rare-earth co-doping which bears testament to the open-framework and rigid nature of these glasses. A range of desirable attributes of these glasses unfold from this finding; in particular, a structural simplicity that will enable facile molecular engineering of rare-earth phosphate glasses with dial-up lasing properties. When considered together with other factors, this finding also demonstrates additional prospects for these co-doped rare-earth phosphate glasses in nuclear waste storage applications. This study also reveals, for the first time, the ability to distinguish between PO and P&amp;z.dbd;O bonding in these rare-earth phosphate glasses from X-ray diffraction data in a fully quantitative manner. Complementary analysis of high-energy X-ray diffraction data on single rare-earth phosphate glasses of similar rare-earth composition to the co-doped materials is also presented in this context. In a technical sense, all high-energy X-ray diffraction data on these glasses are compared with analogous low-energy diffraction data; their salient differences reveal distinct advantages of high-energy X-ray diffraction data for the study of amorphous materials. Rare-earth co-doping in inorganic materials has a long-held tradition of facilitating highly desirable optoelectronic properties for their application to the laser industry.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c3cp44298e</identifier><identifier>PMID: 23518599</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Assessments ; Atomic structure ; Condensed matter: structure, mechanical and thermal properties ; Diffraction ; Exact sciences and technology ; Glass ; Low energy ; Phosphate glass ; Physics ; Rare earth metals ; X-rays</subject><ispartof>Physical chemistry chemical physics : PCCP, 2013-06, Vol.15 (22), p.8529-8543</ispartof><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c434t-1f2abf5b6a2af4f1c5f5ec01f2259aa8cb17cacde0a5cb642f3fa1f4d4fb402d3</citedby><cites>FETCH-LOGICAL-c434t-1f2abf5b6a2af4f1c5f5ec01f2259aa8cb17cacde0a5cb642f3fa1f4d4fb402d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=27393903$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23518599$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cramer, Alisha J</creatorcontrib><creatorcontrib>Cole, Jacqueline M</creatorcontrib><creatorcontrib>FitzGerald, Vicky</creatorcontrib><creatorcontrib>Honkimaki, Veijo</creatorcontrib><creatorcontrib>Roberts, Mark A</creatorcontrib><creatorcontrib>Brennan, Tessa</creatorcontrib><creatorcontrib>Martin, Richard A</creatorcontrib><creatorcontrib>Saunders, George A</creatorcontrib><creatorcontrib>Newport, Robert J</creatorcontrib><title>Effects of rare-earth co-doping on the local structure of rare-earth phosphate glasses using high and low energy X-ray diffraction</title><title>Physical chemistry chemical physics : PCCP</title><addtitle>Phys Chem Chem Phys</addtitle><description>Rare-earth co-doping in inorganic materials has a long-held tradition of facilitating highly desirable optoelectronic properties for their application to the laser industry. This study concentrates specifically on rare-earth phosphate glasses, (R 2 O 3 ) x (R 2 O 3 ) y (P 2 O 5 ) 1( x + y ) , where (R, R) denotes (Ce, Er) or (La, Nd) co-doping and the total rare-earth composition corresponds to a range between metaphosphate, RP 3 O 9 , and ultraphosphate, RP 5 O 14 . Thereupon, the effects of rare-earth co-doping on the local structure are assessed at the atomic level. Pair-distribution function analysis of high-energy X-ray diffraction data ( Q max = 28 1 ) is employed to make this assessment. Results reveal a stark structural invariance to rare-earth co-doping which bears testament to the open-framework and rigid nature of these glasses. A range of desirable attributes of these glasses unfold from this finding; in particular, a structural simplicity that will enable facile molecular engineering of rare-earth phosphate glasses with dial-up lasing properties. When considered together with other factors, this finding also demonstrates additional prospects for these co-doped rare-earth phosphate glasses in nuclear waste storage applications. This study also reveals, for the first time, the ability to distinguish between PO and P&amp;z.dbd;O bonding in these rare-earth phosphate glasses from X-ray diffraction data in a fully quantitative manner. Complementary analysis of high-energy X-ray diffraction data on single rare-earth phosphate glasses of similar rare-earth composition to the co-doped materials is also presented in this context. In a technical sense, all high-energy X-ray diffraction data on these glasses are compared with analogous low-energy diffraction data; their salient differences reveal distinct advantages of high-energy X-ray diffraction data for the study of amorphous materials. Rare-earth co-doping in inorganic materials has a long-held tradition of facilitating highly desirable optoelectronic properties for their application to the laser industry.</description><subject>Assessments</subject><subject>Atomic structure</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Diffraction</subject><subject>Exact sciences and technology</subject><subject>Glass</subject><subject>Low energy</subject><subject>Phosphate glass</subject><subject>Physics</subject><subject>Rare earth metals</subject><subject>X-rays</subject><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqF0UGL1TAQAOAgiruuXrwr8SCIUE2apO_luCy7Kix4UfBWptPJa6WvqZmU5V395fbxnm_Rg54yZL6ZgRkhnmv1Tivj36PBydrSr-mBONe2MoVXa_vwFK-qM_GE-btSSjttHouz0ji9dt6fi5_XIRBmljHIBIkKgpQ7ibFo49SPGxlHmTuSQ0QYJOc0Y54T_cWnLvLUQSa5GYCZWM68L-76TSdhbJfyO0kjpc1OfisS7GTbh5AAcx_Hp-JRgIHp2fG9EF9vrr9cfSxuP3_4dHV5W6A1Nhc6lNAE11RQQrBBowuOUC3fpfMAa2z0CgFbUuCwqWwZTAAdbGtDY1XZmgvx5tB3SvHHTJzrbc9IwwAjxZlr7aqV8r605v_UOKOs035P3x4opsicKNRT6reQdrVW9f489f15Fvzy2HduttSe6O97LOD1EQAvC19WNGLP925lvPFqP_XFwSXGU_aPQa_-la-nNphfTH2v2g</recordid><startdate>20130614</startdate><enddate>20130614</enddate><creator>Cramer, Alisha J</creator><creator>Cole, Jacqueline M</creator><creator>FitzGerald, Vicky</creator><creator>Honkimaki, Veijo</creator><creator>Roberts, Mark A</creator><creator>Brennan, Tessa</creator><creator>Martin, Richard A</creator><creator>Saunders, George A</creator><creator>Newport, Robert J</creator><general>Royal Society of Chemistry</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130614</creationdate><title>Effects of rare-earth co-doping on the local structure of rare-earth phosphate glasses using high and low energy X-ray diffraction</title><author>Cramer, Alisha J ; Cole, Jacqueline M ; FitzGerald, Vicky ; Honkimaki, Veijo ; Roberts, Mark A ; Brennan, Tessa ; Martin, Richard A ; Saunders, George A ; Newport, Robert J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c434t-1f2abf5b6a2af4f1c5f5ec01f2259aa8cb17cacde0a5cb642f3fa1f4d4fb402d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Assessments</topic><topic>Atomic structure</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Diffraction</topic><topic>Exact sciences and technology</topic><topic>Glass</topic><topic>Low energy</topic><topic>Phosphate glass</topic><topic>Physics</topic><topic>Rare earth metals</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cramer, Alisha J</creatorcontrib><creatorcontrib>Cole, Jacqueline M</creatorcontrib><creatorcontrib>FitzGerald, Vicky</creatorcontrib><creatorcontrib>Honkimaki, Veijo</creatorcontrib><creatorcontrib>Roberts, Mark A</creatorcontrib><creatorcontrib>Brennan, Tessa</creatorcontrib><creatorcontrib>Martin, Richard A</creatorcontrib><creatorcontrib>Saunders, George A</creatorcontrib><creatorcontrib>Newport, Robert J</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cramer, Alisha J</au><au>Cole, Jacqueline M</au><au>FitzGerald, Vicky</au><au>Honkimaki, Veijo</au><au>Roberts, Mark A</au><au>Brennan, Tessa</au><au>Martin, Richard A</au><au>Saunders, George A</au><au>Newport, Robert J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of rare-earth co-doping on the local structure of rare-earth phosphate glasses using high and low energy X-ray diffraction</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2013-06-14</date><risdate>2013</risdate><volume>15</volume><issue>22</issue><spage>8529</spage><epage>8543</epage><pages>8529-8543</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>Rare-earth co-doping in inorganic materials has a long-held tradition of facilitating highly desirable optoelectronic properties for their application to the laser industry. This study concentrates specifically on rare-earth phosphate glasses, (R 2 O 3 ) x (R 2 O 3 ) y (P 2 O 5 ) 1( x + y ) , where (R, R) denotes (Ce, Er) or (La, Nd) co-doping and the total rare-earth composition corresponds to a range between metaphosphate, RP 3 O 9 , and ultraphosphate, RP 5 O 14 . Thereupon, the effects of rare-earth co-doping on the local structure are assessed at the atomic level. Pair-distribution function analysis of high-energy X-ray diffraction data ( Q max = 28 1 ) is employed to make this assessment. Results reveal a stark structural invariance to rare-earth co-doping which bears testament to the open-framework and rigid nature of these glasses. A range of desirable attributes of these glasses unfold from this finding; in particular, a structural simplicity that will enable facile molecular engineering of rare-earth phosphate glasses with dial-up lasing properties. When considered together with other factors, this finding also demonstrates additional prospects for these co-doped rare-earth phosphate glasses in nuclear waste storage applications. This study also reveals, for the first time, the ability to distinguish between PO and P&amp;z.dbd;O bonding in these rare-earth phosphate glasses from X-ray diffraction data in a fully quantitative manner. Complementary analysis of high-energy X-ray diffraction data on single rare-earth phosphate glasses of similar rare-earth composition to the co-doped materials is also presented in this context. In a technical sense, all high-energy X-ray diffraction data on these glasses are compared with analogous low-energy diffraction data; their salient differences reveal distinct advantages of high-energy X-ray diffraction data for the study of amorphous materials. Rare-earth co-doping in inorganic materials has a long-held tradition of facilitating highly desirable optoelectronic properties for their application to the laser industry.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><pmid>23518599</pmid><doi>10.1039/c3cp44298e</doi><tpages>15</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1463-9076
ispartof Physical chemistry chemical physics : PCCP, 2013-06, Vol.15 (22), p.8529-8543
issn 1463-9076
1463-9084
language eng
recordid cdi_pubmed_primary_23518599
source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Assessments
Atomic structure
Condensed matter: structure, mechanical and thermal properties
Diffraction
Exact sciences and technology
Glass
Low energy
Phosphate glass
Physics
Rare earth metals
X-rays
title Effects of rare-earth co-doping on the local structure of rare-earth phosphate glasses using high and low energy X-ray diffraction
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T01%3A54%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Effects%20of%20rare-earth%20co-doping%20on%20the%20local%20structure%20of%20rare-earth%20phosphate%20glasses%20using%20high%20and%20low%20energy%20X-ray%20diffraction&rft.jtitle=Physical%20chemistry%20chemical%20physics%20:%20PCCP&rft.au=Cramer,%20Alisha%20J&rft.date=2013-06-14&rft.volume=15&rft.issue=22&rft.spage=8529&rft.epage=8543&rft.pages=8529-8543&rft.issn=1463-9076&rft.eissn=1463-9084&rft_id=info:doi/10.1039/c3cp44298e&rft_dat=%3Cproquest_pubme%3E1353045193%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1353045193&rft_id=info:pmid/23518599&rfr_iscdi=true