[1-(2-Oxidobenzyl-idene)-4-phenyl-thio-semicarbazidato-κO,N,S](pyridine-κN)copper(II)
In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio-amide S atom from the tridentate thio-semicarbazonate dianion, and the N atom o...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-05, Vol.66 (Pt 6), p.m676 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | Pt 6 |
| container_start_page | m676 |
| container_title | Acta crystallographica. Section E, Structure reports online |
| container_volume | 66 |
| creator | Bon, Vladimir V Orysyk, Svitlana I Pekhnyo, Vasily I |
| description | In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio-amide S atom from the tridentate thio-semicarbazonate dianion, and the N atom of a pyridine mol-ecule. The thio-semicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N-H⋯S, C-H⋯O, C-H⋯N and C-H⋯S hydrogen-bonding inter-actions consolidates the structure. |
| doi_str_mv | 10.1107/S1600536810017381 |
| format | Article |
| fullrecord | <record><control><sourceid>pubmed</sourceid><recordid>TN_cdi_pubmed_primary_21579316</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>21579316</sourcerecordid><originalsourceid>FETCH-pubmed_primary_215793163</originalsourceid><addsrcrecordid>eNqFjs0OwUAUhScSUX8PYGPdJi5zW1rWQnTDgsRCRKadK0a0nUxJ1KN5CM-kEtZWJ-f7zuIw1kHeR-TBYI0-5yPPHyPnGHhjrLD6B8GHWayR5-dS-IGLNWa5OAomHvp1tt0h2C6s7kpmEaWP4gJKUkoODEGfKC379aQyyClRsTCReCgprhm8nqvesrfe27owSqqUSrJ04kxrMnYYOi1WPYpLTu1vNll3PttMF6BvUULyoI1KhCkOvyfe38EbvbdDvg</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>[1-(2-Oxidobenzyl-idene)-4-phenyl-thio-semicarbazidato-κO,N,S](pyridine-κN)copper(II)</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><source>PubMed Central Open Access</source><creator>Bon, Vladimir V ; Orysyk, Svitlana I ; Pekhnyo, Vasily I</creator><creatorcontrib>Bon, Vladimir V ; Orysyk, Svitlana I ; Pekhnyo, Vasily I</creatorcontrib><description>In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio-amide S atom from the tridentate thio-semicarbazonate dianion, and the N atom of a pyridine mol-ecule. The thio-semicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N-H⋯S, C-H⋯O, C-H⋯N and C-H⋯S hydrogen-bonding inter-actions consolidates the structure.</description><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S1600536810017381</identifier><identifier>PMID: 21579316</identifier><language>eng</language><publisher>United States</publisher><ispartof>Acta crystallographica. Section E, Structure reports online, 2010-05, Vol.66 (Pt 6), p.m676</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,860,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21579316$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bon, Vladimir V</creatorcontrib><creatorcontrib>Orysyk, Svitlana I</creatorcontrib><creatorcontrib>Pekhnyo, Vasily I</creatorcontrib><title>[1-(2-Oxidobenzyl-idene)-4-phenyl-thio-semicarbazidato-κO,N,S](pyridine-κN)copper(II)</title><title>Acta crystallographica. Section E, Structure reports online</title><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><description>In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio-amide S atom from the tridentate thio-semicarbazonate dianion, and the N atom of a pyridine mol-ecule. The thio-semicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N-H⋯S, C-H⋯O, C-H⋯N and C-H⋯S hydrogen-bonding inter-actions consolidates the structure.</description><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFjs0OwUAUhScSUX8PYGPdJi5zW1rWQnTDgsRCRKadK0a0nUxJ1KN5CM-kEtZWJ-f7zuIw1kHeR-TBYI0-5yPPHyPnGHhjrLD6B8GHWayR5-dS-IGLNWa5OAomHvp1tt0h2C6s7kpmEaWP4gJKUkoODEGfKC379aQyyClRsTCReCgprhm8nqvesrfe27owSqqUSrJ04kxrMnYYOi1WPYpLTu1vNll3PttMF6BvUULyoI1KhCkOvyfe38EbvbdDvg</recordid><startdate>20100519</startdate><enddate>20100519</enddate><creator>Bon, Vladimir V</creator><creator>Orysyk, Svitlana I</creator><creator>Pekhnyo, Vasily I</creator><scope>NPM</scope></search><sort><creationdate>20100519</creationdate><title>[1-(2-Oxidobenzyl-idene)-4-phenyl-thio-semicarbazidato-κO,N,S](pyridine-κN)copper(II)</title><author>Bon, Vladimir V ; Orysyk, Svitlana I ; Pekhnyo, Vasily I</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_215793163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Bon, Vladimir V</creatorcontrib><creatorcontrib>Orysyk, Svitlana I</creatorcontrib><creatorcontrib>Pekhnyo, Vasily I</creatorcontrib><collection>PubMed</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bon, Vladimir V</au><au>Orysyk, Svitlana I</au><au>Pekhnyo, Vasily I</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>[1-(2-Oxidobenzyl-idene)-4-phenyl-thio-semicarbazidato-κO,N,S](pyridine-κN)copper(II)</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><date>2010-05-19</date><risdate>2010</risdate><volume>66</volume><issue>Pt 6</issue><spage>m676</spage><pages>m676-</pages><eissn>1600-5368</eissn><abstract>In the structure of the title compound, [Cu(C(14)H(11)N(3)OS)(C(5)H(5)N)], the Cu(II) atom exhibits a slightly distorted square-planar CuN(2)OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio-amide S atom from the tridentate thio-semicarbazonate dianion, and the N atom of a pyridine mol-ecule. The thio-semicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N-H⋯S, C-H⋯O, C-H⋯N and C-H⋯S hydrogen-bonding inter-actions consolidates the structure.</abstract><cop>United States</cop><pmid>21579316</pmid><doi>10.1107/S1600536810017381</doi></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 1600-5368 |
| ispartof | Acta crystallographica. Section E, Structure reports online, 2010-05, Vol.66 (Pt 6), p.m676 |
| issn | 1600-5368 |
| language | eng |
| recordid | cdi_pubmed_primary_21579316 |
| source | DOAJ Directory of Open Access Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| title | [1-(2-Oxidobenzyl-idene)-4-phenyl-thio-semicarbazidato-κO,N,S](pyridine-κN)copper(II) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T00%3A31%3A04IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=%5B1-(2-Oxidobenzyl-idene)-4-phenyl-thio-semicarbazidato-%CE%BAO,N,S%5D(pyridine-%CE%BAN)copper(II)&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Structure%20reports%20online&rft.au=Bon,%20Vladimir%20V&rft.date=2010-05-19&rft.volume=66&rft.issue=Pt%206&rft.spage=m676&rft.pages=m676-&rft.eissn=1600-5368&rft_id=info:doi/10.1107/S1600536810017381&rft_dat=%3Cpubmed%3E21579316%3C/pubmed%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/21579316&rfr_iscdi=true |