Direct observation of a transient polymorph during crystallization
Application of a technique developed for in situ solid-state 13 C NMR studies of crystallization processes reveals direct evidence that crystallization of glycine from a methanol/water solution involves the initial transient formation of the β polymorph, which then undergoes a solution-mediated poly...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (27), p.4982-4984 |
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| container_end_page | 4984 |
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| container_issue | 27 |
| container_start_page | 4982 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 46 |
| creator | Hughes, Colan E Harris, Kenneth D. M |
| description | Application of a technique developed for
in situ
solid-state
13
C NMR studies of crystallization processes reveals direct evidence that crystallization of glycine from a methanol/water solution involves the initial transient formation of the β polymorph, which then undergoes a solution-mediated polymorphic transformation to yield the more stable α polymorph.
In situ
solid-state
13
C NMR studies yield direct evidence that crystallization of glycine from methanol/water involves the initial transient formation of the β polymorph. |
| doi_str_mv | 10.1039/c0cc01007c |
| format | Article |
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in situ
solid-state
13
C NMR studies of crystallization processes reveals direct evidence that crystallization of glycine from a methanol/water solution involves the initial transient formation of the β polymorph, which then undergoes a solution-mediated polymorphic transformation to yield the more stable α polymorph.
In situ
solid-state
13
C NMR studies yield direct evidence that crystallization of glycine from methanol/water involves the initial transient formation of the β polymorph.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c0cc01007c</identifier><identifier>PMID: 20508878</identifier><language>eng</language><publisher>England</publisher><subject>Beta ; Crystallization ; Glycine ; Methyl alcohol ; Nuclear magnetic resonance ; Transformations</subject><ispartof>Chemical communications (Cambridge, England), 2010-01, Vol.46 (27), p.4982-4984</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c465t-42ccbe6f4f1bb090c1c514de569013a92d18876b60a9f7615f83e4a22ad904f3</citedby><cites>FETCH-LOGICAL-c465t-42ccbe6f4f1bb090c1c514de569013a92d18876b60a9f7615f83e4a22ad904f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27933,27934</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20508878$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hughes, Colan E</creatorcontrib><creatorcontrib>Harris, Kenneth D. M</creatorcontrib><title>Direct observation of a transient polymorph during crystallization</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Application of a technique developed for
in situ
solid-state
13
C NMR studies of crystallization processes reveals direct evidence that crystallization of glycine from a methanol/water solution involves the initial transient formation of the β polymorph, which then undergoes a solution-mediated polymorphic transformation to yield the more stable α polymorph.
In situ
solid-state
13
C NMR studies yield direct evidence that crystallization of glycine from methanol/water involves the initial transient formation of the β polymorph.</description><subject>Beta</subject><subject>Crystallization</subject><subject>Glycine</subject><subject>Methyl alcohol</subject><subject>Nuclear magnetic resonance</subject><subject>Transformations</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqF0U1LwzAYB_AgipvTi3elnhSh-uS1zVHnKwy87OCtpGmila6pSSvMT2_n5nabuSSQH3-eF4SOMVxhoPJag9aAARK9g4aYChZzlr7uLt5cxgllfIAOQviA_mCe7qMBAQ5pmqRDdHtXeqPbyOXB-C_Vlq6OnI1U1HpVh9LUbdS4aj5zvnmPis6X9Vuk_Ty0qqrK719_iPasqoI5Wt0jNH24n46f4snL4_P4ZhJrJngbM6J1boRlFuc5SNBYc8wKw4UETJUkBe5LErkAJW0iMLcpNUwRogoJzNIROl_GNt59dia02awM2lSVqo3rQiYFlZgAS_-VCaUsEZQnvbzYKnEiCCYcc97TyyXV3oXgjc0aX86Un2cYssUass0aeny6yu3ymSnW9G_uPThbAh_0-ncTkDXFouGTbYb-AE62l3U</recordid><startdate>20100101</startdate><enddate>20100101</enddate><creator>Hughes, Colan E</creator><creator>Harris, Kenneth D. M</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20100101</creationdate><title>Direct observation of a transient polymorph during crystallization</title><author>Hughes, Colan E ; Harris, Kenneth D. M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c465t-42ccbe6f4f1bb090c1c514de569013a92d18876b60a9f7615f83e4a22ad904f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Beta</topic><topic>Crystallization</topic><topic>Glycine</topic><topic>Methyl alcohol</topic><topic>Nuclear magnetic resonance</topic><topic>Transformations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hughes, Colan E</creatorcontrib><creatorcontrib>Harris, Kenneth D. M</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hughes, Colan E</au><au>Harris, Kenneth D. M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct observation of a transient polymorph during crystallization</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2010-01-01</date><risdate>2010</risdate><volume>46</volume><issue>27</issue><spage>4982</spage><epage>4984</epage><pages>4982-4984</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Application of a technique developed for
in situ
solid-state
13
C NMR studies of crystallization processes reveals direct evidence that crystallization of glycine from a methanol/water solution involves the initial transient formation of the β polymorph, which then undergoes a solution-mediated polymorphic transformation to yield the more stable α polymorph.
In situ
solid-state
13
C NMR studies yield direct evidence that crystallization of glycine from methanol/water involves the initial transient formation of the β polymorph.</abstract><cop>England</cop><pmid>20508878</pmid><doi>10.1039/c0cc01007c</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2010-01, Vol.46 (27), p.4982-4984 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_pubmed_primary_20508878 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Beta Crystallization Glycine Methyl alcohol Nuclear magnetic resonance Transformations |
| title | Direct observation of a transient polymorph during crystallization |
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