A new method of synthesis of alkyl beta-glycosides using sucrose as sugar donor

Cellobiose phosphorylase from Clostridium thermocellum catalyzed the beta-anomer-selective synthesis of alkyl glucosides from cellobiose. Synthesis of alkyl beta-glucoside from inexpensive sucrose using cellobiose phosphorylase and sucrose phosphorylase from Pseudomonas saccharophilia was investigat...

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Veröffentlicht in:	Bioscience, biotechnology, and biochemistry biotechnology, and biochemistry, 2008-09, Vol.72 (9), p.2415-2417
Hauptverfasser:	Kino, K.(Waseda Univ., Tokyo (Japan). Faculty of Science and Engineering), Satake, R, Morimatsu, T, Kuratsu, S, Shimizu, Y, Sato, M, Kirimura, K
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols - metabolism Biological and medical sciences CELLOBIOSE cellobiose phosphorylase CELOBIOSA CHEMICAL SYNTHESIS CLOSTRIDIUM PASTEURIANUM CLOSTRIDIUM THERMOCELLUM FOSFOPIROLASA Fundamental and applied biological sciences. Psychology GLUCOSIDE GLUCOSIDES Glucosides - metabolism GLUCOSIDOS Glucosyltransferases - metabolism Glycosides - chemical synthesis Glycosides - metabolism MATERIAS PRIMAS MATIERE PREMIERE PHOSPHORYLASE PSEUDOMONAS RAW MATERIALS SACCHAROSE SINTESIS QUIMICA SUCROSA SUCROSE Sucrose - metabolism sucrose phosphorylase SYNTHESE CHIMIQUE β-anomer-selective transglucosylation β-glucoside
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Zusammenfassung:	Cellobiose phosphorylase from Clostridium thermocellum catalyzed the beta-anomer-selective synthesis of alkyl glucosides from cellobiose. Synthesis of alkyl beta-glucoside from inexpensive sucrose using cellobiose phosphorylase and sucrose phosphorylase from Pseudomonas saccharophilia was investigated. By combined use of these two phosphorylases, alkyl beta-glucoside was anomer-selectively synthesized from sucrose and alkyl alcohol.
ISSN:	0916-8451 1347-6947
DOI:	10.1271/bbb.80097