Ion-pair formation in electron recombination with H3

The process of resonant ion-pair formation following electron collisions with is studied. The relevant diabatic potential energy surfaces and the electronic couplings between these surfaces are calculated. The reaction is then described using a time-dependent approach with wave packets propagating o...

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Veröffentlicht in:	Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences physical, and engineering sciences, 2006-11, Vol.364 (1848), p.2999-3005
Hauptverfasser:	Larson, Åsa, Roos, Johanna, Orel, Ann E
Format:	Artikel
Sprache:	eng
Schlagworte:	H3 Ion-Pair State Wave Packet Dynamics
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Beschreibung
Zusammenfassung:	The process of resonant ion-pair formation following electron collisions with is studied. The relevant diabatic potential energy surfaces and the electronic couplings between these surfaces are calculated. The reaction is then described using a time-dependent approach with wave packets propagating on the coupled potentials. In order to describe the reaction, it is found necessary to include at least two dimensions in the model. The effects of the Rydberg states on the cross-section for this process are discussed.
ISSN:	1364-503X 1471-2962
DOI:	10.1098/rsta.2006.1884