Investigations of Ageing Mechanisms for New High-Energy-Density Battery Materials with X-Ray Spectrometry

XRS, traceable to the International System of Units, enables the quantitative determination of elemental mass depositions on a very large dynamic range that can be used to investigate, for example the transition metal deposition at the solid electrolyte interphase (SEI) in currently used lithium-Ion...

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Veröffentlicht in:Spectroscopy 2020-07, Vol.35 (7), p.39-40
Hauptverfasser: Zech, Claudia, Kayser, Yves, Honicke, Philipp, Beckhoff, Burkhard
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Honicke, Philipp
Beckhoff, Burkhard
description XRS, traceable to the International System of Units, enables the quantitative determination of elemental mass depositions on a very large dynamic range that can be used to investigate, for example the transition metal deposition at the solid electrolyte interphase (SEI) in currently used lithium-Ion batteries (LIBs). [...]even the oxidation state and the species of an element, which plays a major role regarding ageing mechanisms, can be specified with XRS. Given that the ageing processes in the battery are time dependent, reliable analytical operando methods are needed that allow for the correlation of analytical information with the electrochemical performance. [...]the dissolved polysulfides can travel in the electrolyte solution through the cell and the movement between the electrodes is called polysulfide shuttle. Reaching the anode, further damaging effects can occur because of polysulfides undergoing reactions in the negative potentials. [...]polysulfides have to be studied not only on the cathode side but also in the near-anode region.
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subjects Ageing
Aging
Anodes
Batteries
Cathodes
Company legal issue
Electrochemical analysis
Electrochemistry
Electrolytes
Energy
International System of Units
Investigations
Lithium
Lithium-ion batteries
Metals
Oxidation
Pollutant deposition
Polysulfides
Radiation
Rechargeable batteries
Scientific imaging
Solid electrolytes
Spectrometry
Transition metals
Valence
X-ray spectroscopy
title Investigations of Ageing Mechanisms for New High-Energy-Density Battery Materials with X-Ray Spectrometry
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