Communication: Multi-state analysis of the OCS ultraviolet absorption including vibrational structure
The first absorption band of OCS (carbonyl sulfide) is analyzed using potential energy surfaces and transition dipole moment functions of the lowest four singlet and the lowest four triplet states. Excitation of the 2 1 A ′ state is predominant except at very low photon energies. It is shown that th...
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| Veröffentlicht in: | The Journal of chemical physics 2012-04, Vol.136 (13), p.131101-131101-4 |
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| Sprache: | eng |
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| container_end_page | 131101-4 |
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| container_issue | 13 |
| container_start_page | 131101 |
| container_title | The Journal of chemical physics |
| container_volume | 136 |
| creator | Schmidt, J. A. Johnson, M. S. McBane, G. C. Schinke, R. |
| description | The first absorption band of OCS (carbonyl sulfide) is analyzed using potential energy surfaces and transition dipole moment functions of the lowest four singlet and the lowest four triplet states. Excitation of the 2
1
A
′
state is predominant except at very low photon energies. It is shown that the vibrational structures in the center of the band are due to excitation of the 2
3
A
′
′
triplet state, whereas the structures at very low energies are caused by bending excitation in the potential wells of states 2
1
A
′
and 1
1
A
′
′
. |
| doi_str_mv | 10.1063/1.3701699 |
| format | Article |
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1
A
′
state is predominant except at very low photon energies. It is shown that the vibrational structures in the center of the band are due to excitation of the 2
3
A
′
′
triplet state, whereas the structures at very low energies are caused by bending excitation in the potential wells of states 2
1
A
′
and 1
1
A
′
′
.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.3701699</identifier><identifier>PMID: 22482532</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><ispartof>The Journal of chemical physics, 2012-04, Vol.136 (13), p.131101-131101-4</ispartof><rights>2012 American Institute of Physics</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c439t-6d1afbbad6259a9fa8b09e5dc6eb60a04ee0c57cf94429341f66ffbcc75719f3</citedby><cites>FETCH-LOGICAL-c439t-6d1afbbad6259a9fa8b09e5dc6eb60a04ee0c57cf94429341f66ffbcc75719f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,792,1556,4500,27907,27908</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22482532$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schmidt, J. A.</creatorcontrib><creatorcontrib>Johnson, M. S.</creatorcontrib><creatorcontrib>McBane, G. C.</creatorcontrib><creatorcontrib>Schinke, R.</creatorcontrib><title>Communication: Multi-state analysis of the OCS ultraviolet absorption including vibrational structure</title><title>The Journal of chemical physics</title><addtitle>J Chem Phys</addtitle><description>The first absorption band of OCS (carbonyl sulfide) is analyzed using potential energy surfaces and transition dipole moment functions of the lowest four singlet and the lowest four triplet states. Excitation of the 2
1
A
′
state is predominant except at very low photon energies. It is shown that the vibrational structures in the center of the band are due to excitation of the 2
3
A
′
′
triplet state, whereas the structures at very low energies are caused by bending excitation in the potential wells of states 2
1
A
′
and 1
1
A
′
′
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1
A
′
state is predominant except at very low photon energies. It is shown that the vibrational structures in the center of the band are due to excitation of the 2
3
A
′
′
triplet state, whereas the structures at very low energies are caused by bending excitation in the potential wells of states 2
1
A
′
and 1
1
A
′
′
.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><pmid>22482532</pmid><doi>10.1063/1.3701699</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | The Journal of chemical physics, 2012-04, Vol.136 (13), p.131101-131101-4 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_993102415 |
| source | AIP Journals Complete; AIP Digital Archive; Alma/SFX Local Collection |
| title | Communication: Multi-state analysis of the OCS ultraviolet absorption including vibrational structure |
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