Carbon Dioxide Mediated Stereoselective Copper-Catalyzed Reductive Coupling of Alkynes and Thiols

A simple protocol for the stereoselective copper-catalyzed hydrothiolation of alkynes under a CO2 atmosphere has been developed. The stereoselectivity is determined by the presence/absence of a CO2 atmosphere. The reaction system is robust and utilizes inexpensive, readily available substrates. A cy...

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Veröffentlicht in:	Organic letters 2012-04, Vol.14 (7), p.1780-1783
Hauptverfasser:	Nurhanna Riduan, Siti, Ying, Jackie Y, Zhang, Yugen
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes - chemistry Carbon Dioxide - chemistry Catalysis Copper - chemistry Molecular Structure Stereoisomerism Sulfhydryl Compounds - chemistry Sulfides - chemical synthesis Sulfides - chemistry Water - chemistry
Online-Zugang:	Volltext
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