Synthesis of Bromo-, Boryl-, and Stannyl-Functionalized 1,2-Bis(trimethylsilyl)benzenes via Diels–Alder or C–H Activation Reactions

1,2-Bis­(trimethylsilyl)­benzenes are key starting materials for the synthesis of benzyne precursors, Lewis acid catalysts, and certain luminophores. We have developed efficient, high-yield routes to functionalized 4-R-1,2-bis­(trimethylsilyl)­benzenes, starting from either 1,2-bis­(trimethylsilyl)­...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of organic chemistry 2012-04, Vol.77 (7), p.3518-3523
Hauptverfasser:	Reus, Christian, Liu, Nai-Wei, Bolte, Michael, Lerner, Hans-Wolfram, Wagner, Matthias
Format:	Artikel
Sprache:	eng
Schlagworte:	B derivatives Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Noncondensed benzenic compounds Organic chemistry Organometalloidal and organometallic compounds Preparations and properties Si derivatives Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!