Enantioresolution of 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl Oxide Using Inclusion Complex with Chiral 2,2′-Dihydroxy-1,1′-binaphtyl
An enantioresolution of 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl oxide (BINAPO) into its enantiomers was achieved using the inclusion complex with a commercially available chiral 2,2′-dihydroxy-1,1′-binaphthyl ((R)-BINOL), giving the two enantiomers with 99% ee and 72% ee, respectively.
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| Veröffentlicht in: | Journal of organic chemistry 2012-04, Vol.77 (7), p.3595-3597 |
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| container_end_page | 3597 |
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| container_issue | 7 |
| container_start_page | 3595 |
| container_title | Journal of organic chemistry |
| container_volume | 77 |
| creator | Hatano, Bunpei Hashimoto, Kazuyuki Katagiri, Hiroshi Kijima, Tatsuro Murakami, Satoshi Matsuba, Shigeru Kusakari, Miho |
| description | An enantioresolution of 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl oxide (BINAPO) into its enantiomers was achieved using the inclusion complex with a commercially available chiral 2,2′-dihydroxy-1,1′-binaphthyl ((R)-BINOL), giving the two enantiomers with 99% ee and 72% ee, respectively. |
| doi_str_mv | 10.1021/jo202630p |
| format | Article |
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Org. Chem</addtitle><date>2012-04-06</date><risdate>2012</risdate><volume>77</volume><issue>7</issue><spage>3595</spage><epage>3597</epage><pages>3595-3597</pages><issn>0022-3263</issn><eissn>1520-6904</eissn><coden>JOCEAH</coden><abstract>An enantioresolution of 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl oxide (BINAPO) into its enantiomers was achieved using the inclusion complex with a commercially available chiral 2,2′-dihydroxy-1,1′-binaphthyl ((R)-BINOL), giving the two enantiomers with 99% ee and 72% ee, respectively.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>22397310</pmid><doi>10.1021/jo202630p</doi><tpages>3</tpages></addata></record> |
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| ispartof | Journal of organic chemistry, 2012-04, Vol.77 (7), p.3595-3597 |
| issn | 0022-3263 1520-6904 |
| language | eng |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Catalysis Chemistry Condensed benzenic and aromatic compounds Exact sciences and technology Molecular Structure Naphthalenes - chemical synthesis Naphthalenes - chemistry Noncondensed benzenic compounds Organic chemistry Organometalloidal and organometallic compounds P derivatives Phosphines - chemical synthesis Phosphines - chemistry Preparations and properties Stereoisomerism |
| title | Enantioresolution of 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl Oxide Using Inclusion Complex with Chiral 2,2′-Dihydroxy-1,1′-binaphtyl |
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