Design of an efficient photocatalytic reactor for the decomposition of gaseous organic contaminants in air

[Display omitted] ► Linear velocity for the designed reactor was optimized for photocatalytic reaction. ► Fiber based support for immobilizing TiO2 improved the photocatalytic performance. ► Optimum photocatalytic system for degradation of organic pollutant was designed. ► Suggested reactor exhibite...

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Veröffentlicht in:Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2012-04, Vol.187, p.203-209
Hauptverfasser: Lee, David Minzae, Yun, Hyeong Jin, Yu, Sungju, Yun, Seong Jin, Lee, Sun Young, Kang, Sang Hyeon, Yi, Jongheop
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container_start_page 203
container_title Chemical engineering journal (Lausanne, Switzerland : 1996)
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creator Lee, David Minzae
Yun, Hyeong Jin
Yu, Sungju
Yun, Seong Jin
Lee, Sun Young
Kang, Sang Hyeon
Yi, Jongheop
description [Display omitted] ► Linear velocity for the designed reactor was optimized for photocatalytic reaction. ► Fiber based support for immobilizing TiO2 improved the photocatalytic performance. ► Optimum photocatalytic system for degradation of organic pollutant was designed. ► Suggested reactor exhibited very high stability for photocatalytic reaction. Here, a strategy for decomposing gaseous organic contaminants by photocatalytic reactions is reported. A photocatalytic reactor is designed, based on an open tubular reactor with a UV light source installed at the center of the glass tube to permit the vertical irradiation of light onto the photocatalyst. TiO2 immobilized on a stainless steel plate and a fiber based material, respectively, are placed on the inner wall of an open tubular reactor. The fibers of felt induce wake and eddy flow near the inner surface of the reactor, resulting in compression of boundary layer. The compressed boundary layer provides a higher probability of contact between organic contaminants and the photocatalyst, consequently resulting in the enhanced photocatalytic oxidative decomposition of organic compounds. The inlet of photoreactor is modified in order to better control the bulk stream to form spiral-like flow. The reactor with a single tangent inlet exhibits the highest photocatalytic performance among the reactors examined, as an evidence of the improved probability of contact. Importantly, the reactor with a single tangent inlet, in which TiO2 immobilized felt is installed, maintains its photocatalytic activities for as long as twenty days.
doi_str_mv 10.1016/j.cej.2012.01.121
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Here, a strategy for decomposing gaseous organic contaminants by photocatalytic reactions is reported. A photocatalytic reactor is designed, based on an open tubular reactor with a UV light source installed at the center of the glass tube to permit the vertical irradiation of light onto the photocatalyst. TiO2 immobilized on a stainless steel plate and a fiber based material, respectively, are placed on the inner wall of an open tubular reactor. The fibers of felt induce wake and eddy flow near the inner surface of the reactor, resulting in compression of boundary layer. The compressed boundary layer provides a higher probability of contact between organic contaminants and the photocatalyst, consequently resulting in the enhanced photocatalytic oxidative decomposition of organic compounds. The inlet of photoreactor is modified in order to better control the bulk stream to form spiral-like flow. 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Importantly, the reactor with a single tangent inlet, in which TiO2 immobilized felt is installed, maintains its photocatalytic activities for as long as twenty days.</description><subject>air</subject><subject>Air purification</subject><subject>Applied sciences</subject><subject>Catalysis</subject><subject>Catalytic reactions</subject><subject>Chemical engineering</subject><subject>Chemistry</subject><subject>Contact</subject><subject>Contact probability</subject><subject>Contaminants</subject><subject>Exact sciences and technology</subject><subject>Fibers</subject><subject>General and physical chemistry</subject><subject>glass</subject><subject>Inlets</subject><subject>irradiation</subject><subject>organic compounds</subject><subject>Photocatalysis</subject><subject>probability</subject><subject>Reactor design</subject><subject>Reactors</subject><subject>stainless steel</subject><subject>Tangents</subject><subject>Theory of reactions, general kinetics. Catalysis. 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identifier ISSN: 1385-8947
ispartof Chemical engineering journal (Lausanne, Switzerland : 1996), 2012-04, Vol.187, p.203-209
issn 1385-8947
1873-3212
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source ScienceDirect Journals (5 years ago - present)
subjects air
Air purification
Applied sciences
Catalysis
Catalytic reactions
Chemical engineering
Chemistry
Contact
Contact probability
Contaminants
Exact sciences and technology
Fibers
General and physical chemistry
glass
Inlets
irradiation
organic compounds
Photocatalysis
probability
Reactor design
Reactors
stainless steel
Tangents
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
TiO2
Titanium dioxide
ultraviolet radiation
title Design of an efficient photocatalytic reactor for the decomposition of gaseous organic contaminants in air
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